Monomeric Indium(I) and Silver(I) Complexes of a Polyfluorinated Tris(pyrazolyl)borate

Inorganic Chemistry

Volumn 35, Issue 1, 1996, Pages 267-268

  Dias, H V Rasika ^a   Jin, Wiechang ^a  

^a UNIVERSITY OF TEXAS AT ARLINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001273479     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic950901m     Document Type: Article

References (23)

1. Tuck, D. G. Chem. Rev. 1993, 93, 269.
2. Beachley, O. T., Jr.; Lees, J. F.; Rogers, R. D. J. Organomet. Chem, 1991, 418, 165.
3. Dias, H. V. R.; Huai, L; Jin, W.; Bott, S. G. Inorg Chem, 1995, 34, 1973.
4. Frazer, A.; Piggott, B.; Hursthouse, M. B.; Mazid, M. J Am. Chem. Soc. 1994, 116, 4127.
5. Frazer, A.; Piggott. B.; Harman, M.; Mazid, M.; Hursthouse, M. B. Polyhedron 1992, 11, 3013.
6. Dias, H. V. R.; Lu, H. L.; Ratcliff, R. E.; Bott, S. G. Inorg. Chem. 1995, 34, 1975.
7. 3 and for related references: Gassman, P. G.; Mickelson, J. W.; Sowa, J. R., Jr. J. Am. Chem. Soc. 1992, 114, 6942.
8. Dias, H. V. R.; Lu, H. L. Inorg. Chem. 1995, 34, 5380.
9. Fluorinated aryloxide has been used previously to obtain a dimeric In(I) species, Scholz, M.; Noltemeyer, M.; Roesky, H. W. Angew. Chem., Int. Ed. Engl. 1989, 28, 1383.
10. 6AgOB: C. 28.49: H, 1.51: N, 10.49. Found: C. 28.69: H. 1.23: N, 10.18.
11. Bruce, M. I; Walsh, J. D. Aust. J. Chem. 1979, 32, 2753.
12. See, for other examples involving long range coupling to fluorine: Emsley, J. W.; Phillips, L.; Wray, V. Fluorine Coupling Constants: Pergamon Press: New York, 1977.
13. Hilton, J.; Sutcliffe, L. H. In Progress in NMR Spearoscapy; Emsley, J. W., Feeney, J., Sutcliffe, L. H., Eds.; Pergamon Press: New York, 1975; Vol. 10: pp 27-39.
14. 2. resulting from the disproportionation of InCl was also observed in some of the runs. See Supporting Information for the X-ray structural data for this molecule
15. 19F NMR: δ-59.31 (s), -59.76 (d)): Dias, H. V. R.; Jin, W. Unpublished data
16. w = 3.06% for 1470 reflections with F > 4σ(F). and 202 parameters.
17. Orpen, A. G.; Brammer, L.; Allen, F. H.; Kennard. O.; Watson, D. G.; Taylor, R. J. Chem. Soc., Dalton Trans. 1989, S1.
18. Lancashire, R. J. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCIeverty, J. A., Eds.; Pergamon Books Ltd.; New York, 1987; Vol. 5, p 775
19. Trofimenko, S. Chem. Rev. 1993, 93, 943.
20. Purdy, A. P.; George, C. F. In Inorganic Fluorine Chemistry, Toward the 21st Century; Thrasher, J. S., Strauss, S. H., Eds.; ACS Symposium Series 555; American Chemical Society: Washington, DC, 1994, p 413.
21. Jones, P. G.; Gries, T.; Grutzmacher, H.; Roesky, H. W.; Schimkowiak, J.; Sheldrick, G. M. Angew. Chem., Int. Ed. Engl. 1984, 23, 376.
22. Uson, R.; Fornies, J., Tomas, M.; Casas, J. M.; Cotton, F. A.; Falvello, L. R. Inorg. Chem. 1987, 26, 3482.
23. Brace, M. I.; Walsh, J. D.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 1981, 956.