Confinement-induced phase transitions in simple liquids

Science

Volumn 269, Issue 5225, 1995, Pages 816-819

  Klein, Jacob ^a   Kumacheva, Eugenia ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001273008     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.269.5225.816     Document Type: Article

References (44)

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26. See, for example, I. Bitsanis, J. Magda, M. Tirrell, H. T. Davis, ibid. 87, 1733 (1987); U. Landman, W. D. Luedtke, M. W. Ribarsky, J. Vac. Sci. Technol. A 7, 2829 (1989); M. Schoen, C. L Rhykerd Jr., D. J. Diestler, J. H. Cushman, Science 245, 1223 (1989); P. A. Thompson and M. O. Robbins, ibid. 250, 792 (1990); P. A. Thompson, G. S. Grest, M. O. Robbins, Phys. Rev. Lett. 68, 3448 (1992); D. J. Diestler, M. Schoen, J. H. Cushman, Science 262, 545 (1993).
27. See, for example, I. Bitsanis, J. Magda, M. Tirrell, H. T. Davis, ibid. 87, 1733 (1987); U. Landman, W. D. Luedtke, M. W. Ribarsky, J. Vac. Sci. Technol. A 7, 2829 (1989); M. Schoen, C. L Rhykerd Jr., D. J. Diestler, J. H. Cushman, Science 245, 1223 (1989); P. A. Thompson and M. O. Robbins, ibid. 250, 792 (1990); P. A. Thompson, G. S. Grest, M. O. Robbins, Phys. Rev. Lett. 68, 3448 (1992); D. J. Diestler, M. Schoen, J. H. Cushman, Science 262, 545 (1993).
28. See, for example, I. Bitsanis, J. Magda, M. Tirrell, H. T. Davis, ibid. 87, 1733 (1987); U. Landman, W. D. Luedtke, M. W. Ribarsky, J. Vac. Sci. Technol. A 7, 2829 (1989); M. Schoen, C. L Rhykerd Jr., D. J. Diestler, J. H. Cushman, Science 245, 1223 (1989); P. A. Thompson and M. O. Robbins, ibid. 250, 792 (1990); P. A. Thompson, G. S. Grest, M. O. Robbins, Phys. Rev. Lett. 68, 3448 (1992); D. J. Diestler, M. Schoen, J. H. Cushman, Science 262, 545 (1993).
29. See, for example, I. Bitsanis, J. Magda, M. Tirrell, H. T. Davis, ibid. 87, 1733 (1987); U. Landman, W. D. Luedtke, M. W. Ribarsky, J. Vac. Sci. Technol. A 7, 2829 (1989); M. Schoen, C. L Rhykerd Jr., D. J. Diestler, J. H. Cushman, Science 245, 1223 (1989); P. A. Thompson and M. O. Robbins, ibid. 250, 792 (1990); P. A. Thompson, G. S. Grest, M. O. Robbins, Phys. Rev. Lett. 68, 3448 (1992); D. J. Diestler, M. Schoen, J. H. Cushman, Science 262, 545 (1993).
30. See, for example, I. Bitsanis, J. Magda, M. Tirrell, H. T. Davis, ibid. 87, 1733 (1987); U. Landman, W. D. Luedtke, M. W. Ribarsky, J. Vac. Sci. Technol. A 7, 2829 (1989); M. Schoen, C. L Rhykerd Jr., D. J. Diestler, J. H. Cushman, Science 245, 1223 (1989); P. A. Thompson and M. O. Robbins, ibid. 250, 792 (1990); P. A. Thompson, G. S. Grest, M. O. Robbins, Phys. Rev. Lett. 68, 3448 (1992); D. J. Diestler, M. Schoen, J. H. Cushman, Science 262, 545 (1993).
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35. J. Klein, D. Perahia, S. Warburg, L. J. Fetters, Nature 352, 143 (1991); J. Klein, E. Kumacheva, D. Mahalu, D. Perahia, L. J. Fetters, ibid. 370, 634 (1994); J. Klein, E. Kumacheva, D. Perahia, D. Mahalu, S. Warburg, Faraday Spec. Discuss. Chem. Soc., in press.
36. J. Klein, D. Perahia, S. Warburg, L. J. Fetters, Nature 352, 143 (1991); J. Klein, E. Kumacheva, D. Mahalu, D. Perahia, L. J. Fetters, ibid. 370, 634 (1994); J. Klein, E. Kumacheva, D. Perahia, D. Mahalu, S. Warburg, Faraday Spec. Discuss. Chem. Soc., in press.
37. 5.
38. R. W. K. Honeycombe, The Plastic Deformation of Metals (Arnold, London, 1984), chap. 6.
39. We find that, as for a ductile solid, the yield stress at a given normal stress is essentially independent of shear velocity.
40. eff of ∼3 P.
41. 2.
42. E. Kumacheva and J. Klein, unpublished data.
43. This is in contrast to earlier reports of such a regime in a number of liquids (including OMCTS) (10, 20). These earlier reports were concerned with thinner films under significant compression, where different effects may play a role. Further work will be required to clarify the relation between the different studies.
44. We thank R. Ball, S. Granick, G. Grest, J. Israelachvili, M. Lahav, L. Leiserovicz, and M. Bobbins for useful discussions and comments. This work was supported by the Israel Science Foundation, the Commission of the European Community, and the Ministry of Science and Arts (Israel) together with the Kernforschunaszentrum (Jülich, Germany).