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85034127632
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note
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zz(0) for the push-pull polyene molecules considered here.
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32
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85034123831
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-
note
-
max 481 (cyclohexane), 479 (dioxane), 480 (diethyl oxide), 486 (ethyl acetate), 494 (tetrahydrofuran), 503 (dichloromethane), 498 (acetone), 497 (acetonitrile), 507 (DMF), 513 (DMSO).
-
-
-
-
35
-
-
85034149989
-
-
note
-
The EFISH technique is described in ref 19. In these papers, the quadratic polarizabilities are given in the X convention of ref 34. The quadratic polarizability in the Taylor series convention, used in this work, is 4 times that of the X convention.
-
-
-
-
36
-
-
85034138351
-
-
-9 esu at 1.907 μm)
-
-9 esu at 1.907 μm).
-
-
-
-
37
-
-
85034150828
-
-
zzz(2ω)
-
zzz(2ω).
-
-
-
-
38
-
-
85034149465
-
-
The Pockels EO contribution given here in the Taylor convention differs by a factor 2 from that in ref 20, where the perturbation series convention B of ref 34 was used
-
The Pockels EO contribution given here in the Taylor convention differs by a factor 2 from that in ref 20, where the perturbation series convention B of ref 34 was used.
-
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39
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note
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g) in the analysis referred to above indicates that the angle factors probably cannot account for the calculated and measured magnitude differences in the molecules 3[2] and 5[2] (cf. Section IV).
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59
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0001174929
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in this connection
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2b on the nonlinear optical properties of the molecules may be accounted for in the effective VB treatment. Nevertheless, it would be interesting to examine molecules in which there is no such aromatic ring, to clearly assess its influence. See also: Hernandez, V.; Castiglioni, C.; Del Zoppo, M.; Zerbi, G. Phys. Rev. B 1994, 50, 9815 in this connection.
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Work in progress
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Plaza, P.; Laage, D.; Martin, M.; Alain, V.; Blanchard-Desce, M.; Hynes, J. T. Work in progress.
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