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Volumn 71, Issue 8, 1993, Pages 1192-1195

Neutron diffraction study of the structure of deuterated ice VIII to 10 GPa

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[No Author keywords available]

Indexed keywords


EID: 0001267718     PISSN: 00319007     EISSN: None     Source Type: Journal    
DOI: 10.1103/PhysRevLett.71.1192     Document Type: Article
Times cited : (106)

References (26)
  • 8
    • 84927459550 scopus 로고    scopus 로고
    • R. J. Nelmes, J. S. Loveday, and J. M. Besson, in Accuracy in Powder Diffraction II, Proceedings of the International Conference, edited by E. Prince and J. K. Stalick National Institute of Standards and Technology Special Publication No. 846 (U.S. G.P.O., Washington, DC, 1992), p. 195.
  • 14
    • 84927507440 scopus 로고    scopus 로고
    • I. Olovsson and P-G. Jönsson, in The Hydrogen Bond. Recent Developments in Theory and Experiments, edited by P. Schuster, G. Zundel, and C. Sandorfy (North-Holland, Amsterdam, 1976), Vol. II, p. 395.
  • 16
    • 84927479937 scopus 로고    scopus 로고
    • The empirical relationship used in Ref. [3] gives a value of 3.7 times 10-3 A ang ^_GPa-1 for partial ( O - H ) / partial P, but is based on a much smaller set of values than that used in Refs. [14] and [15].
  • 21
    • 84927507154 scopus 로고    scopus 로고
    • D2O is used rather than H2O because hydrogen gives a high background level of incoherent scattering in neutron-diffraction spectra.
  • 26
    • 84927461967 scopus 로고    scopus 로고
    • No corrections have been applied to the O-D bond lengths for the librational motion of D relative to the O atom. But the corrections will be small and vary little with pressure, and hence will have only a very small effect on the rate of change of O-D. The sense of the correction would be to reduce very slightly the rate of change because thermal amplitudes are expected to decrease with pressure.


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