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Volumn 577, Issue 2, 1999, Pages 189-196

Redox properties of the 17-electron sandwich (η5-C5H5)Mo(η6-C 6Ph6): Electrochemical characterization of the 16 e- Lewis acid monocation and its PF6- adduct

Author keywords

17 Electron; Electrochemistry; Metallocene; Molybdenum

Indexed keywords


EID: 0001265350     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)01038-9     Document Type: Article
Times cited : (9)

References (47)
  • 15
    • 85034558107 scopus 로고    scopus 로고
    • The crystal structure of 1 was obtained at 173 K by M.A. Mazid and M.B. Hursthouse at the University of Wales, Cardiff. The arene ring is planar to within 0.01 Å
    • The crystal structure of 1 was obtained at 173 K by M.A. Mazid and M.B. Hursthouse at the University of Wales, Cardiff. The arene ring is planar to within 0.01 Å.
  • 16
    • 85034562534 scopus 로고    scopus 로고
    • -1
    • -1.
  • 17
    • 0343567046 scopus 로고
    • - height and decreases or eliminates the anodic component of the wave. It is an example of homogeneous redox catalysis see
    • - height and decreases or eliminates the anodic component of the wave. It is an example of homogeneous redox catalysis (see C.P. Andrieux, P. Hapiot, J.-M. Saveant, Chem. Rev. 90 (1990) 723).
    • (1990) Chem. Rev. , vol.90 , pp. 723
    • Andrieux, C.P.1    Hapiot, P.2    Saveant, J.-M.3
  • 18
    • 85034562622 scopus 로고    scopus 로고
    • 1/2 over the range of scan rates
    • 1/2 over the range of scan rates.
  • 20
    • 85034547854 scopus 로고    scopus 로고
    • p(A)=0.77, and the measured value is 0.68
    • p(A)=0.77, and the measured value is 0.68.
  • 21
    • 0345808194 scopus 로고
    • 1/2 value. For more on the implications of a Nernstian wave see in: S.J. Lippard (Ed.), Wiley, New York
    • 1/2 value. For more on the implications of a Nernstian wave see W.E. Geiger, in: S.J. Lippard (Ed.), Progress in Inorganic Chemistry, vol. 33, Wiley, New York, 1985, pp. 277-281.
    • (1985) Progress in Inorganic Chemistry , vol.33 , pp. 277-281
    • Geiger, W.E.1
  • 22
    • 85034538785 scopus 로고    scopus 로고
    • (a) in Ref. 4
    • (a) W.E. Geiger, in Ref. 4, p. 142
    • Geiger, W.E.1
  • 44
    • 0347700215 scopus 로고
    • (b)
    • (b) Ibid 112 (1979) 3715.
    • (1979) Chem. Ber. , vol.112 , pp. 3715
  • 45
    • 85034551242 scopus 로고    scopus 로고
    • + from the heights of voltammetric waves. To do so we must assume that the diffusion coefficients of the two species are identical, an approximation that is difficult to verify without isolation of the species involved
    • + from the heights of voltammetric waves. To do so we must assume that the diffusion coefficients of the two species are identical, an approximation that is difficult to verify without isolation of the species involved.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.