Convenient synthesis of dichloro(oxo)(pentamethylcyclopentadienyl)vanadium(V), (η-C5Me5)V(O)Cl2

Organometallics

Volumn 16, Issue 9, 1997, Pages 1994-1996

  Aistars, Amis ^a   Newton, Claire ^a   Rübenstahl, Thilo ^a   Doherty, Nancy M ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001261941     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960625z     Document Type: Article

References (37)

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2. For a general introduction to the topic, see: Bottomley, F.; Sutin, L. Adv. Organomet. Chem. 1988, 28, 339-396. Herrmann, W. A. Comments Inorg. Chem. 1988, 7, 73-107. Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; Wiley: New York, 1988.
3. For a general introduction to the topic, see: Bottomley, F.; Sutin, L. Adv. Organomet. Chem. 1988, 28, 339-396. Herrmann, W. A. Comments Inorg. Chem. 1988, 7, 73-107. Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; Wiley: New York, 1988.
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28. Overall yield of 2 using air is good with little, if any, evidence for formation of hydrolysis products in our hands.
29. We have not succeeded in preparing 1 in any useful yield using other CsMes reagents.
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35. See, for example: Studies in Surface Science and Catalysis, 66. Dioxygen Activation and Homogeneous Catalytic Oxidation; Simandi, L. I., Ed.; Elsevier: Amsterdam, 1991. Oxygen Complexes and Oxygen Activation by Transition Metals; Martell, A. E., Sawyer, D. T., Eds.; Plenum: New York, 1988. Sheldon, R. A.; Kochi, J. K. Metal-Catalyzed Oxidations of Organic Compounds; Academic Press: New York, 1981.
36. See, for example: Studies in Surface Science and Catalysis, 66. Dioxygen Activation and Homogeneous Catalytic Oxidation; Simandi, L. I., Ed.; Elsevier: Amsterdam, 1991. Oxygen Complexes and Oxygen Activation by Transition Metals; Martell, A. E., Sawyer, D. T., Eds.; Plenum: New York, 1988. Sheldon, R. A.; Kochi, J. K. Metal-Catalyzed Oxidations of Organic Compounds; Academic Press: New York, 1981.
37. See, for example: Studies in Surface Science and Catalysis, 66. Dioxygen Activation and Homogeneous Catalytic Oxidation; Simandi, L. I., Ed.; Elsevier: Amsterdam, 1991. Oxygen Complexes and Oxygen Activation by Transition Metals; Martell, A. E., Sawyer, D. T., Eds.; Plenum: New York, 1988. Sheldon, R. A.; Kochi, J. K. Metal-Catalyzed Oxidations of Organic Compounds; Academic Press: New York, 1981.