The first structural characterization of a [2.2]PHANEPHOS-transition-metal complex: Structure of rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl2]

Organometallics

Volumn 17, Issue 20, 1998, Pages 4344-4346

  Dyer, Philip W ^a   Dyson, Paul J ^b   James, Stuart L ^b   Martin, Caroline M ^c   Suman, Priya ^b  

^a UNIVERSITY OF LEICESTER   (United Kingdom)

^b IMPERIAL COLLEGE LONDON   (United Kingdom)

^c UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001260453     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980416+     Document Type: Article

References (22)

1. Kagan, H. B.; Sasaki, M. In The Chemistry of Organophosphorus Compounds; Hartley, F. R., Ed.; John Wiley: New York, 1990; Vol. 1.
2. Gilheany, D. G.; Mitchel, C. M. In ref 1.
3. Noyori, R. Asymmetric Catalysis in Organic Synthesis; Wiley: New York, 1994.
4. Ojima, I. Catalytic Asymmetric Synthesis; VCH: Weinheim, Germany, 1994.
5. Pye, P. J.; Rossen, K.; Reamer, R. A.; Tsou, N. N.; Volante, R. P.: Reider, P. J. J. Am. Chem. Soc. 1997, 119, 6207.
6. Rossen, K.; Weissman, S. A.; Sager, J.; Reamer, R. A.; Askin, D.; Volante, R. P.; Reider, P. J. Tetrahedron Lett. 1995, 36, 6419.
7. Rossen, K.; Pye, P. J.; Maliakal, A.; Volante, R. P. J. Org. Chem. 1997, 62, 6462.
8. +).
9. Garrou, P. E. Chem. Rev. 1981, 81, 229.
10. Dyson, P. J.; Suman, P. Imperial College of Science, Technology and Medicine, unpublished results.
11. Roundhill, R. M. In Comprehensive Coordination Chemistry; Wilkinson, G., McCleverty, J. M., Eds.; Pergamon: Oxford, U.K., 1987.
12. -1) and 430 parameters (all non-H atoms anisotropic except solvent molecule). The structure was solved by direct methods (Sheldrick, G. M. SHELXS 86, Program for Crystal Structure Solution Acta Crystallogr., Sect. A 1990, 46, 467), and a series of difference Fourier maps were used to locate all light atoms except the H atoms. The H atoms were then added in calculated positions (C-H=0.96 Å) riding on the respective C atoms. All other calculations were performed using SHELXL 93 (Sheldrick, G. M. SHELXS 93, Program for Crystal Structure Refinement; University of Göttingen, Göttingen, Germany, 1993). Compound 1 crystallises with a dichloromethane solvent molecule in the asymmetric unit, which is disordered over two sites. Atomic coordinates, anisotropic thermal parameters, and bond lengths and angles have been deposited at the Cambridge Crystallographic Data Centre. See Information for Authors, Issue No. 1.
13. -1) and 430 parameters (all non-H atoms anisotropic except solvent molecule). The structure was solved by direct methods (Sheldrick, G. M. SHELXS 86, Program for Crystal Structure Solution Acta Crystallogr., Sect. A 1990, 46, 467), and a series of difference Fourier maps were used to locate all light atoms except the H atoms. The H atoms were then added in calculated positions (C-H=0.96 Å) riding on the respective C atoms. All other calculations were performed using SHELXL 93 (Sheldrick, G. M. SHELXS 93, Program for Crystal Structure Refinement; University of Göttingen, Göttingen, Germany, 1993). Compound 1 crystallises with a dichloromethane solvent molecule in the asymmetric unit, which is disordered over two sites. Atomic coordinates, anisotropic thermal parameters, and bond lengths and angles have been deposited at the Cambridge Crystallographic Data Centre. See Information for Authors, Issue No. 1.
14. Cambridge Crystallographic Data Centre.
15. Kranenburg, M.; Kamer, P. C. J.; van Leeuwen, P. W. N. M. Eur. J. Inorg. Chem. 1998, 155.
16. Steffen, W. L.; Palenik, G. J. Inorg. Chem. 1976, 15, 2432.
17. Ozawa, F.; Kubo, A.: Matsumoto, Y.; Hayashi, T.; Nishioka, E.; Yanagi, K.; Moriguchi, K. Organometaltics 1993, 12, 4188.
18. Hayashi, T.; Konishi, M.; Kobori, Y.; Kumada, M.; Higuchi, T.; Hirotsu, K. J. Am. Chem. Soc. 1984, 106, 158.
19. Butler, I. R.; Cullen, W. R.; Kim, T.-J.; Reltig, S. J.; Trotter, J. Organometallics 1985, 4, 972.
20. Hill, W. E.; Taylor, J. G.; Falshaw, C. P.; King, T. J.; Beagley, B.; Tonge, D. M.; Pritchard, R. G.; McAuliffe, C. A. J. Chem. Soc., Dalton Trans. 1986, 2289.
21. Brown, J. M.; Guiry, P. J. Inorg. Chim. Acta 1994, 220, 249.
22. Dekker, G. P. C. M.; Elsevier, C. J.; Vrieze, K.; van Leeuwen, P. W, N. M.; Roobeek, C. F. J. Organomet. Chem. 1992, 430, 357.