Insertion into the strained silicon-carbon bond of a silicon-bridged [1]ferrocenophane: Synthesis and structure of a [2]platinasilaferrocenophane

Organometallics

Volumn 15, Issue 9, 1996, Pages 2195-2197

  Sheridan, John B ^a,b   Lough, Alan J ^b   Manners, Ian ^b  

^a RUTGERS UNIVERSITY   (United States)

^b UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001259149     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960033g     Document Type: Article

References (41)

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17. Desulfurization-induced ROP of trisulfido-bridged [3]ferrocenophanes has also been reported; see: Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367.
18. Desulfurization-induced ROP of trisulfido-bridged [3]ferrocenophanes has also been reported; see: Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367.
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31. 5
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35. Cundy, C. S.; Eaborn, C.; Lappert, M. F. J. Organomet. Chem. 1972, 44, 291 and references cited therein.
36. For the insertion of Fe into a silacyclobutane: (a) Cundy, C. S.; Lappert, M. F. J. Chem. Soc., Chem. Comm. 1972, 445. (b) Cundy, C. S.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1976, 910. (c) Cundy, C. S.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1978, 665.
37. For the insertion of Fe into a silacyclobutane: (a) Cundy, C. S.; Lappert, M. F. J. Chem. Soc., Chem. Comm. 1972, 445. (b) Cundy, C. S.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1976, 910. (c) Cundy, C. S.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1978, 665.
38. For the insertion of Fe into a silacyclobutane: (a) Cundy, C. S.; Lappert, M. F. J. Chem. Soc., Chem. Comm. 1972, 445. (b) Cundy, C. S.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1976, 910. (c) Cundy, C. S.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1978, 665.
39. For insertion of Pt into a silacyclobutane, see: Yamashita, H.; Tanaka, M.; Hinda, K. J. Am. Chem. Soc. 1995, 117, 8873.
40. 2PtSi: C, 42.80; H, 6.53. Found: C, 42.77; H, 6.68.
41. -3 (largest three peaks in residual electron density map within 1.0 Å from the Pt atom).