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Hydrosilation: see ref 4
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(a) Hydrosilation: see ref 4. (b) Diels Alder: Evans, D. A.; Murry, J. A.; Von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (c) Mukaiyama Aldol reaction: Evans, D. A.; Murry, J. A.; Kozlowski, M. C. J. Am. Chem. Soc. 1996, 118, 5814. (d) Cyclopropanation: Gupta, A. D.; Bhuniya, D.; Singh, V. K. Tetrahedron 1994, 50, 13725. (e) Nishiyama, H.; Itoh, Y.; Matsumoto, H.; Park, B. B.; Itoh, K. J. Am. Chem. Soc. 1994, 116, 2223. (f) Aldol reaction of isocyanoacetates: J. Organomet. Chem. 1996, 507, 85.
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12
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33748726159
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Diels Alder
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(a) Hydrosilation: see ref 4. (b) Diels Alder: Evans, D. A.; Murry, J. A.; Von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (c) Mukaiyama Aldol reaction: Evans, D. A.; Murry, J. A.; Kozlowski, M. C. J. Am. Chem. Soc. 1996, 118, 5814. (d) Cyclopropanation: Gupta, A. D.; Bhuniya, D.; Singh, V. K. Tetrahedron 1994, 50, 13725. (e) Nishiyama, H.; Itoh, Y.; Matsumoto, H.; Park, B. B.; Itoh, K. J. Am. Chem. Soc. 1994, 116, 2223. (f) Aldol reaction of isocyanoacetates: J. Organomet. Chem. 1996, 507, 85.
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0030017687
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Mukaiyama Aldol reaction
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(a) Hydrosilation: see ref 4. (b) Diels Alder: Evans, D. A.; Murry, J. A.; Von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (c) Mukaiyama Aldol reaction: Evans, D. A.; Murry, J. A.; Kozlowski, M. C. J. Am. Chem. Soc. 1996, 118, 5814. (d) Cyclopropanation: Gupta, A. D.; Bhuniya, D.; Singh, V. K. Tetrahedron 1994, 50, 13725. (e) Nishiyama, H.; Itoh, Y.; Matsumoto, H.; Park, B. B.; Itoh, K. J. Am. Chem. Soc. 1994, 116, 2223. (f) Aldol reaction of isocyanoacetates: J. Organomet. Chem. 1996, 507, 85.
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0027986439
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Cyclopropanation
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(a) Hydrosilation: see ref 4. (b) Diels Alder: Evans, D. A.; Murry, J. A.; Von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (c) Mukaiyama Aldol reaction: Evans, D. A.; Murry, J. A.; Kozlowski, M. C. J. Am. Chem. Soc. 1996, 118, 5814. (d) Cyclopropanation: Gupta, A. D.; Bhuniya, D.; Singh, V. K. Tetrahedron 1994, 50, 13725. (e) Nishiyama, H.; Itoh, Y.; Matsumoto, H.; Park, B. B.; Itoh, K. J. Am. Chem. Soc. 1994, 116, 2223. (f) Aldol reaction of isocyanoacetates: J. Organomet. Chem. 1996, 507, 85.
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0000139463
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(a) Hydrosilation: see ref 4. (b) Diels Alder: Evans, D. A.; Murry, J. A.; Von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (c) Mukaiyama Aldol reaction: Evans, D. A.; Murry, J. A.; Kozlowski, M. C. J. Am. Chem. Soc. 1996, 118, 5814. (d) Cyclopropanation: Gupta, A. D.; Bhuniya, D.; Singh, V. K. Tetrahedron 1994, 50, 13725. (e) Nishiyama, H.; Itoh, Y.; Matsumoto, H.; Park, B. B.; Itoh, K. J. Am. Chem. Soc. 1994, 116, 2223. (f) Aldol reaction of isocyanoacetates: J. Organomet. Chem. 1996, 507, 85.
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Aldol reaction of isocyanoacetates
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(a) Hydrosilation: see ref 4. (b) Diels Alder: Evans, D. A.; Murry, J. A.; Von Matt, P.; Norcross, R. D.; Miller, S. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 798. (c) Mukaiyama Aldol reaction: Evans, D. A.; Murry, J. A.; Kozlowski, M. C. J. Am. Chem. Soc. 1996, 118, 5814. (d) Cyclopropanation: Gupta, A. D.; Bhuniya, D.; Singh, V. K. Tetrahedron 1994, 50, 13725. (e) Nishiyama, H.; Itoh, Y.; Matsumoto, H.; Park, B. B.; Itoh, K. J. Am. Chem. Soc. 1994, 116, 2223. (f) Aldol reaction of isocyanoacetates: J. Organomet. Chem. 1996, 507, 85.
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85034552152
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note
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Determined by GC using a Supelco BETA-DEX 120 fused silica capilliary column. Conditions were set up such that both starting material and endo and exo isomers of the product could be detected. Another injection under modified conditions allowed the detection of both enantiomers of the major isomer, allthough full base-line resolution could not be obtained.
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Williams, J.M.J.4
Coote, S.J.5
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