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The excited state of the complex does not exactly corresponds to the case where the two unit charges are separated by the D-A distance. The dipole moment in the excited state in smaller than the one suggested by such a simple consideration (ref 31).
-
The excited state of the complex does not exactly corresponds to the case where the two unit charges are separated by the D-A distance. The dipole moment in the excited state in smaller than the one suggested by such a simple consideration (ref 31).
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2h) for several reasons: (a) the complex is weak, so the vibrational modes are localized (modes in the complex localized on the acceptor are almost the same as on the acceptor itself); (b) it is much more informative to use this symmetry description than to describe them in terms of low symmetry complex; (c) the symmetry of the complex in solution is not well defined.
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