Reactivity of a 1-azavinylidene ligand with diphenylacetylene on a ruthenium carbonyl cluster. A remarkable alkyne insertion into a metal-nitrogen bond

Organometallics

Volumn 16, Issue 13, 1997, Pages 2763-2764

  Cabeza, Javier A ^a   Del Río, Ignacio ^a   Franco, R Jesús ^a   Grepioni, Fabrizia ^b   Riera, Víctor ^a  

^a UNIVERSITY OF OVIEDO   (Spain)

^b UNIVERSITY OF BOLOGNA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001251964     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970259z     Document Type: Article

References (22)

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2. For reviews on late-transition-metal amido complexes, see: (a) Fryzuk, M. D.; Montgomery, C. D. Coord. Chem. Rev. 1989, 95, 1. (b) Bryndza, H. E. Chem. Rev. 1988, 88, 1163.
3. For reviews on bi- and polynuclear ruthenium complexes containing N-donor ligands, see: (a) Cabeza, J. A.; Fernández-Colinas, J. M. Coord. Chem. Rev. 1993, 126, 319. (b) Bruce, M. I.; Cifuentes, M. P.; Humphrey, M. G. Polyhedron 1991, 10, 277.
4. For reviews on bi- and polynuclear ruthenium complexes containing N-donor ligands, see: (a) Cabeza, J. A.; Fernández-Colinas, J. M. Coord. Chem. Rev. 1993, 126, 319. (b) Bruce, M. I.; Cifuentes, M. P.; Humphrey, M. G. Polyhedron 1991, 10, 277.
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9. (e) Rahim, M.; Bushweller, C. H.; Ahmed, K. J. Organometallics 1994, 13, 4952 and references therein.
10. (a) Cabeza, J. A.; Riera, V.; Pellinghelli, M. A.; Tiripicchio, A. J. Organomet. Chem. 1989, 376, C23.
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12. See, for example: (a) Cowan, R. L.; Trogler, W. C. J. Am. Chem. Soc. 1989, 111, 4750. (b) Bryndza, H. E.; Fultz, W. C.; Tam, W. Organometallics 1985, 4, 939.
13. See, for example: (a) Cowan, R. L.; Trogler, W. C. J. Am. Chem. Soc. 1989, 111, 4750. (b) Bryndza, H. E.; Fultz, W. C.; Tam, W. Organometallics 1985, 4, 939.
14. 2]: Van der Lende, D. D.; Abboud, K. A.; Boncella, J. M. Inorg. Chem. 1995, 34, 5319.
15. Andreu, P. L.; Cabeza, J. A.; del Rio, I.; Riera, V.; Bois, C. Organometallics 1996, 15, 3004.
16. See, for example: (a) Daniel, T.; Knaup, W.; Dziallas, M.; Werner, H. Chem. Ber. 1993, 126, 1981. (b) Esteruelas, M. A.; Lahoz, F. J.; Olivan, M.; Oñate, E.; Oro, L. A. Organometallics 1994, 13, 3315.
17. See, for example: (a) Daniel, T.; Knaup, W.; Dziallas, M.; Werner, H. Chem. Ber. 1993, 126, 1981. (b) Esteruelas, M. A.; Lahoz, F. J.; Olivan, M.; Oñate, E.; Oro, L. A. Organometallics 1994, 13, 3315.
18. 3, 290 K): 7.6-6.5 (m, 27 H), 5.76 (d, 7.6 Hz, 1 H), 5.04 (d, 7.6 Hz, 1 H) ppm.
19. 10c Two crystallographically independent molecules were found in the asymmetric unit. All non-H atoms were treated anisotropically. H atoms were refined using a riding model,
20. (b) Sheldrick, G. M. Acta Crystallogr., Sect. A 1990, 46, 467.
21. (c) Sheldrick, G. M. SHELXL92, Program for Crystal Structure Determination; University of Göttingen: Göttingen, Germany, 1993.
22. See, for example: Cabeza, J. A.; Fernández-Colinas, J. M.; Llamazares, A.; Riera, V. Organometallics 1992, 11, 4355 and references therein.