An unusual iron-oxo tetranuclear species: Li2(HDPhF)2Fe4O4(DPhF)6 · 4toluene. A ubiquitous side product in the chemistry of iron/formamidine compounds

Inorganica Chimica Acta

Volumn 252, Issue 1-2, 1996, Pages 293-298

  Cotton, F Albert ^a   Daniels, Lee M ^a   Maloney, David J ^a   Murillo, Carlos A ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

Author keywords

Crystal structures; Eight membered complexes; Formamidine complexes; Hydrogen bonds; Iron complexes; Oxo complexes

Indexed keywords

ATOMS; CRYSTAL ATOMIC STRUCTURE; CRYSTAL STRUCTURE; HYDROGEN BONDS; LITHIUM ALLOYS; NEGATIVE IONS;

CENTROSYMMETRIC; COORDINATION ENVIRONMENT; EIGHT-MEMBERED COMPLEXES; FORMAMIDINES; IRON COMPLEX; OXO COMPLEXES; SIDE PRODUCTS; STRUCTURAL CHARACTERIZATION;

IRON COMPOUNDS;

EID: 0001242877     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(96)05328-5     Document Type: Article

References (25)

1. F.A. Cotton and R.A. Walton, Multiple Bonds Between Metal Atoms, Oxford University Press, Oxford, UK, 2nd edn., 1993.
2. (a) F.A. Cotton, L.M. Daniels, D.J. Maloney and C.A. Murillo, Inorg. Chim. Acta, 242 (1996) 31;
3. (b) F.A. Cotton, L.M. Daniels and C.A. Murillo, Inorg. Chem., 32 (1993) 2881;
4. (c) F.A. Cotton and W.A. Wojtczak, Polyhedron, 13 (1994) 1337.
5. F.A. Cotton, L.M. Daniels, L.R. Falvello and C.A. Murillo, Inorg. Chim. Acta, 219 (1994) 7.
6. F.A. Cotton, L.M. Daniels and C.A. Murillo, Inorg. Chim. Acta, 224 (1994) 5.
7. J. A Clark, M. Kilner and A. Pietrzykowski, Inorg. Chim. Acta, 82 (1984) 85.
8. See for example: (a) M. Mikuriya, Y. Hashimoto and S. Nakashima, Chem. Commun., (1996) 295;
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19. (b) D.I. Arnold, F.A. Cotton, D.J. Maloney, J.H. Matonic and C.A. Murillo, Polyhedron, accepted.
20. See for example Table II in: L. Que, Jr. and A.E. True, Prog. Inorg. Chem., 38 (1990) 97.
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23. (b) S.M. Gorun, G.C. Papaefthymiou, R.B. Frankel and S.J. Lippard, J. Am. Chem. Soc., 109 (1987) 3337;
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