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p-Dinitrobenzene was found to directly react with 4 in the presence of NaH without CuI to give ethyl 2-cyano-2-(4-nitrophenyl)propionate, whereas the m-isomer did not. Such a nucleophilic substitution of p-dinitrobenzene was previously reported: N. Kornblum, L. Cheng, R. C. Kerber, M. M. Kestner, B. N. Newton, H. W. Pinnick, R. G. Smith, and P. A. Wade, J. Org. Chem., 41, 1560 (1976).
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