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Volumn 105, Issue 14, 1996, Pages 5817-5829

Microscopic description of nonadiabatic, nonequilibrium, and equilibrium solvations for solvated cluster reactions: (H2O)nCl-+CH3CI→CICH 3+CI-(H2O)n

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EID: 0001239563     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.472424     Document Type: Article
Times cited : (38)

References (67)
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    • note
    • Although Cameron et al. (Réf. 50) had explained the relation between the rate constant and the pressure on the basis of activation volume, Sumi et al. (Ref. 49) demonstrated that the relation may be understood by assuming solvent-fluctuation control.
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    • The frictional effects for the nonreactive modes in the solute coordinates are expected to promote the reaction progress. The discussion is given in Refs. 34 and 56.
    • The frictional effects for the nonreactive modes in the solute coordinates are expected to promote the reaction progress. The discussion is given in Refs. 34 and 56.


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