Trinuclear Gold(I) Pyrazolate Complexes Exhibiting Hexagonal Columnar Mesophases with only Three Side Chains

Chemistry of Materials

Volumn 10, Issue 7, 1998, Pages 1889-1893

  Kim, Sung Jee ^a   Kang, Seok Ho ^a   Park, Ki Min ^a   Kim, Heesub ^b   Zin, Wang Cheol ^a   Choi, Moon Gun ^c   Kim, Kimoon ^a  

^a Center for Smart Suprarnolecules   (South Korea)

^b Pohang University of Science and Technology (POSTECH)   (South Korea)

^c Yonsei University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001238579     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm9800534     Document Type: Article

References (24)

1. A preliminary account of the work was presented at the 78th annual meeting of the Korean Chemical Society on October 18, 1996 (Program and Abstract p285).
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18. -1, however, the same phase behavior was observed, except that the transition temperatures were shifted to higher temperatures by ∼20 °C in all complexes.
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23. In Figure 3, the sharp low-angle peaks due to the hexagonal columnar arrangement of the gold complex are so intense that the high-angle region appears to be almost featureless. It is therefore difficult to judge any possible intracolumnar ordering, such as persistence of the "dimer" structure in the meaophase, from the X-ray diffraction data.
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