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This paper contains a survey of distances in pentagonal-bipyramidal peroxomolybdates.
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One example is the [MoO2(O2)(C2O4)(H2O)]2− anion
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It is interesting to note that protonation of a peroxo ligand need not convert it to the ɳ1 form. A crystal structure of a complex containing the [H{VO(02)2bpy}2]− anion shows protonation at an oxygen of an ɳ−bound peroxo group. This does result in a substantial lengthening of that V-O peroxo bond. See
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It is interesting to note that protonation of a peroxo ligand need not convert it to the ɳ1 form. A crystal structure of a complex containing the [H{VO(02)2bpy}2]− anion shows protonation at an oxygen of an ɳ−bound peroxo group. This does result in a substantial lengthening of that V-O peroxo bond. See: Szentivanyi, H.; Stomberg, R. Acta Chem. Scand., Ser. A 1984, A38, 101.
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