Iodomethane oxidation by dimethyldioxirane: A new route to hypoiodous acid and iodohydrines

Organic Letters

Volumn 1, Issue 13, 1999, Pages 2125-2128

  Asensio, Gregorio ^a   Andreu, Cecilia ^a   Boix Bernardini, Carmen ^a   Mello, Rossella ^a   González Nuñez, María Elena ^a  

^a UNIVERSITY OF VALENCIA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001231358     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol9903281     Document Type: Article

References (41)

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41. 4 and the solvent removed under vacuum. GC-MS analysis of the reaction mixture showed in most cases the nearly total conversion of 5 into the expected iodohydrine 6 and the presence of variable amounts of 2-iodopropanone. Products were purified by column chromatography (silica, hexane:ethyl acetate 95:5).