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Volumn 120, Issue 18, 1998, Pages 4540-4541

Generation and reactivity of a triplet 1, 4-biradical conformationally trapped in a crystalline cyclopentanone

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EID: 0001228196     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja980112e     Document Type: Letter
Times cited : (35)

References (30)
  • 10
    • 0004290301 scopus 로고
    • Patai, S., Pappoport, Z., Eds.; John Wiley & Sons Ltd.: New York
    • Schuster, D. I. In The Photochemistry of Enones; Patai, S., Pappoport, Z., Eds.; John Wiley & Sons Ltd.: New York, 1989; pp 623-756.
    • (1989) The Photochemistry of Enones , pp. 623-756
    • Schuster, D.I.1
  • 17
    • 0642284350 scopus 로고
    • Cyclopentanone 1 was prepared by hydrogenation of 2,6- benzylidenecyclopentanone followed by reaction with tBuOK and MeI. Compounds 2 and 3 were prepared from 2,2-diphenylcyclopentanone (Easton, N. R.; Nelson, S. J. J. Am. Chem. Soc. 1953, 75, 640) by reaction with MeI and tBuOK, and by reaction with pentaphenyl bismuth
    • (1953) J. Am. Chem. Soc. , vol.75 , pp. 640
    • Easton, N.R.1    Nelson, S.J.2
  • 23
    • 0001385580 scopus 로고
    • Although high stereospecificity in the cyclization of singlet 1,4-biradicals suggests that product formation competes with conformational equilibration, 1,4-biradicals from azo precursors cyclize and cleave with similar probabilities: Bartlett, P. D.; Porter, N. A. J. Am. Chem. Soc. 1968, 90, 5317-5319.
    • (1968) J. Am. Chem. Soc. , vol.90 , pp. 5317-5319
    • Bartlett, P.D.1    Porter, N.A.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.