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Tetrahedron Letters

Volumn 29, Issue 32, 1988, Pages 3967-3970

Asymmetric ene reaction catalyzed by chiral organoaluminum reagent

(4) Maruoka, Keiji a Hoshino, Yorihisa a Shirasaka, Tadashi a Yamamoto, Hisashi a

a NAGOYA UNIVERSITY (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001226063 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4039(00)80395-0 Document Type: Article

Times cited : (165)

References (23)

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2
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6
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7
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8
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9
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- Asymmetric induction in the ene reaction of chloral with (1S,5S)-(?)-?-pinene; control of stereoselectivity by the choice of Lewis acid catalyst
- For related reactions, see
- (1977) Journal of the Chemical Society, Chemical Communications , pp. 382
- Gill¹ Wallace²

10
- 0000143741
- Regio- and stereo-selective syntheses of cyclic natural products by intramolecular cycloaddition- and ene-reactions
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- Oppolzer¹

11
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12
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13
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14
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- For intramolecular ene reactions of unsaturated aldehydes catalyzed by a chiral Lewis acid, see
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- Sakane¹ Maruoka² Yamamoto³

15
- 0000995013
- (1986) Tetrahedron , vol.42 , pp. 2203
- Sakane¹ Maruoka² Yamamoto³

16
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- Prepared in 90% yield by the reaction of PhSSPh with CH2=C(Me)Li in Hf at −78 °C for 1 h.

17
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- (1988) J. Am. Chem. Soc. , vol.110 , pp. 310
- Maruoka¹ Itoh² Shirasaka³ Yamamoto⁴

18
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- Available from Aldrich Chemical Company Inc.

19
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- Several asymmetric reactions were successfully improved to a catalytic process by the use of molecular sieves
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- Hanson¹ Sharpless²

20
- 0003051940
- The asymmetric Diels-Alder reaction by the use of a catalytic amount of a chiral titanium reagent.
- (1986) Chemistry Letters , pp. 1967
- Narasaka¹ Inoue² Yamada³

21
- 0000597958
- Stereocontrolled [m + n] annulation reactions. 2. A [3 + 3] route to chiral, nonracemic 1,2-cyclohexanediols
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- Gao¹ Hanson² Klunder³ Ko⁴ Masamune⁵ Sharpless⁶

22
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- −1.

23
- 84918462639
- 3Al and (R)-(+)-3,3′-diphenylbinaphthol under the comparable conditions as described in Table 1 (entry 20) gave entirely the racemic product in low yield.

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