The shape of the nonlocal dielectric function of polar liquids and the implications for thermodynamic properties of electrolytes: A comparative study

Journal of Chemical Physics

Volumn 104, Issue 4, 1996, Pages 1524-1544

  Kornyshev, Alexei A ^a,b   Sutmann, Godehard ^a  

^a FORSCHUNGSZENTRUM JÜLICH   (Germany)

^b FRUMKIN INSTITUTE OF PHYSICAL CHEMISTRY AND ELECTROCHEMISTRY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001226011     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.470741     Document Type: Article

References (66)

1. R. R. Dogonadze, A. A. Kornyshev, and A. M. Kuznetsov, Teor. Mat. Fiz. 15, No. 1, 127 (1973).
2. R. R. Dogonadze and A. A. Kornyshev, JCS Faraday II 70, No. 6, 1121 (1974).
3. A. A. Kornyshev, Electrochimica Acta 26, 1 (1981).
4. A. A. Kornyshev, in The Chemical Physics of Salvation, edited by R. R. Dogonadze, E. Kaiman, A. A. Komyshev, and L. Ulstrup (Elsevier Science, Amsterdam, 1985), Vol. Part A, ch. 3, p. 77.
5. See Sec. 3, in A. A. Komyshev and W. Schmickler, J. Electroanal. Chem. 202, 1 (1986).
6. M. A. Vorotyntsev, in The Chemical Physics of Salvation, edited by R. R. Dogonadze, E. Kaiman, A. A. Kornyshev, and J. Ulstrup (Elsevier Science, Amsterdam, 1985), Vol. Part C, ch.7, p. 401.
7. M. A. Vorotyntsev and A. A. Kornyshev, Electrostatics of Media with Spatial Dispersion (in Russian) (Nauka, Moscow, 1993).
8. A. A. Kornyshev and M. A. Vorotyntsev, Surf. Sci. 101, 23 (1980).
9. M. A. Vorotyntsev and A. A. Kornyshev, Elektrokhimiya 15, No. 5, 660 (1979).
10. M. A. Vorotyntsev and A. A. Kornyshev, Zh. Exper. Teor. Fiz. 78, No. 5, 1008 (1980).
11. A. A. Kornyshev, W. Schmickler, and M. A. Vorotyntsev, Phys. Rev B 25, 5244 (1982).
12. A. A. Kornyshev and J. Ulstrup, Chem. Scr. 25, 58 (1985).
13. M. A. Vorotyntsev, V. Y. Izotov, and A. A. Kornyshev, Poverkhnost Fiz. Khim. Mekh. 7, 97 (1983).
14. P. G. Dzhavakhidze, A. A. Kornyshev, and L. I. Krishtalik, J. Electroanal. Chem. 228, 329 (1987).
15. A. M. Berezhkovskii, S. A. Kabakchi, A. A. Kornyshev, and G. E. Chudinov, Dokl. AN SSSR 307, 625 (1989).
16. D. L. Phelps, A. A. Kornyshev, and M. J. Weaver, J. Phys. Chem. 94, 1454 (1990).
17. L. I. Krishtalik, N. M. Alpatova, and E. V. Ovsyannikova, Electrochim. Acta 36, 435 (1991).
18. K. Holub and A. A. Kornyshev, J. C. S. Faraday 2 76, 67 (1980).
19. M. Neumann, Mol. Phys. 57, 97 (1986).
20. D. Bertolini and A. Tani, Mol. Phys. 75, 1065 (1992).
21. F. O. Rainen, H. Resat, and H. L. Friedman, J. Chem. Phys. 96, 3068 (1992).
22. B. Bagchi, J. Chem. Phys. 95, 467 (1991).
23. A. Chandra and B. Bagchi, J. Chem. Phys. 90, 1832 (1989).
24. A. Chandra and B. Bagchi, J. Chem. Phys. 91, 3056 (1989).
25. P. Attard, D. Wei, and G. N. Patey, Chem. Phys. Let. 172, 69 (1990).
26. T. Fonseca and B. M. Ladanyi, J. Chem. Phys. 93, 8148 (1990).
27. T. Fonseca and B. M. Ladanyi, in Condensed Matter Physics Aspects of Electrochemistry, edited by M. P. Tosi and A. A. Kornyshev (World Scientific, Singapore, 1991), p. 79.
28. F. O. Rainen, Y. Zhou, and H. L. Friedman, Chem. Phys. 152, 201 (1991).
29. Ph. A. Bopp, A. A. Kornyshev, and G. Sutmann, Phys. Rev. Lett, (to be published).
30. O. V. Dolgov, D. A. Kirzhnits, and E. G. Maksimov, Rev. Mod. Phys. 53, 81 (1981).
31. A. A. Kornyshev, D. A. Kossakowski, and M. A. Vorotyntsev, in Condensed Matter Physics Aspects of Electrochemistry, edited by M. P. Tosi and A. A. Kornyshev (World Scientific, Singapore, 1991), p. 92.
32. R. R. Dogonadze and A. A. Komyshev, Elektrokhimiya 9, 1321 (1973).
33. M. S. Skaf, T. Fonseca, and B. M. Ladanyi, J. Chem. Phys. 98, 8929 (1993).
34. We refer to this type of ∈(k), containing a wrong limiting behavior for k→∞ with ACFN (Attard et al.; Chandra and Bagchi; Fonseca and Ladanyi; Neumann). Although the principle of calculation of ∈(k) [using the Fourier transform of the total dipol moment M(k) for the calculation] seems to be the same in Refs. 20 and 33 we do not include these works into this class (ACFN), as only calculations were performed in the very small k-region.
35. A. A. Kornyshev, S. Leikin, and G. Sutmann, Electrochim. Acta (in press).
36. k→x ∈(k)<0.
37. * by ∞ would give misleading results (Ref. 36).
38. P. P. Schmidt and J. M. McKinley, J. C. S. Faraday 2 72, 143 (1976).
39. B. S. Gourary and F. J. Adrian, Solid State Phys. 10, 127 (1960).
40. L. Pauling, The Nature of the Chemical Bond (Cornell University, Ithaca, 1948).
41. A. F. C. Ladd, Theor. Chim. Acta 12, 333 (1968).
42. M. F. Golovko and I. R. Yukhnovskij, in The Chemical Physics of Salvation, edited by R. R. Dogonadze, E. Kaiman, A. A. Kornyshev, and J. Ulstrup (Elsevier Science, Amsterdam, 1985), p. 207.
43. M. Revere, R. Miniero, M. Parinello, and M. P. Tosi, Phys. Chem. Liq. 9, 11 (1979).
44. 2 and γ> >λ (for BKLS: λ = 0.15 Å, γ=3 Å), ∈(k) shows in the small k region a Lorentzian-type behavior with a corresponding correlation length ∧ = γ.
45. A. A. Kornyshev and A. G. Volkov, J. Electroanal. Chem. 180, 363 (1984).
46. M. Salomon, J. Phys. Chem. 74, 2519 (1970).
47. J. E. B. Randies, Trans. Faraday Soc. 52, 1573 (1956).
48. K. Holub and A. A. Kornyshev, Z. Naturforsch. Tell A31, 1601 (1976).
49. H. Falkenhagen and W. Ebeling, in Ionic Interactions, edited by S. Petrucci (Academic, New York, 1971), Vol. 1, p. 1.
50. A. A. Kornyshev, Chem. Scr. 25, 63 (1985).
51. H. S. Harned and B. B. Owen, The Physical Chemistry of Electrolyte Solutions (Reinhold, New York, 1950).
52. R. A. Robinson and R. H. Stokes, Electrolyte Solutions (Butterworth, London, 1965).
53. W. Ebeling and H. Krienke, in The Chemical Physics of Salvation, edited by R. R. Dogonadze, E. Kaiman, A. A. Kornyshev, and J. Ulstrup (Elsevier, Amsterdam, 1986), Vol. Part C, Chap. 2, p. 113.
54. G. Kelbg, Z. Phys. Chem. 214, 8, 26, 141, 153 (1960).
55. H. L. Friedman and J. C. Rasaiah, J. Chem. Phys. 48, 2742 (1968).
56. J. C. Rasaiah and H. L. Friedman, J. Chem. Phys. 50, 3965 (1969).
57. H. L. Friedman and C. V. Krishnan, in Water - A Comprehensive Treatise, edited by F. Franks (Plenum, New York, 1973), Vol. 3.
58. E. Bich, W. Ebeling, and H. Krienke, Z. Phys. Chem. 257, 549 (1976).
59. H. Wiechert, H. Krienke, R. Feistel, and W. Ebeling, Z. Phys. Chem. 259, 1057 (1978).
60. H. Krienke and P. Faigl, Wiss. Z. WPU Rostock 27, 887 (1978).
61. W. Ebeling, R. Feistel, and R. Sandig, J. Sol. Chem. 8, 53 (1979).
62. Cl-≃0.52 (Ref. 40) or ≃0.71 (Ref. 39).
63. R. H. Stokes and R. A. Robinson, J. Am. Chem. Soc. 70, 1870 (1949).
64. W. A. Harrison, Solid State Theory (McGraw-Hill, New York, 1970).
65. 4
66. M. A. Vorotyntsev, J. Phys. C 11, 3323 (1978).