Origin, spectral characteristics and practical applications of the cathodoluminescence (CL) of quartz - A review

Mineralogy and Petrology

Volumn 71, Issue 3-4, 2001, Pages 225-250

  Gotze J ^a   Plotze M ^b   Habermann, D ^a  

^a TU BERGAKADEMIE FREIBERG   (Germany)

^b ETH ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CATHODOLUMINESCENCE; ELECTRON SPIN RESONANCE; FLUID FLOW; LATTICE DYNAMICS; LUMINESCENCE DATING; PROVENANCE; QUARTZ; ULTRAVIOLET RADIATION;

EID: 0001223249     PISSN: 09300708     EISSN: None     Source Type: Journal    
DOI: 10.1007/s007100170040     Document Type: Article

References (92)

1. Agel A (1992) Paramagnetische Defektzentren in polykristallinem Quarz granitischer und metamorpher Herkunft. Thesis, University of Marburg, 109 p (unpublished)
2. 2. J Appl Phys 54: 5369-5375
3. 2. Solid State Comm 48: 551-556
4. Bambauer HU (1961) Spurenelementgehalte und Farbzentren in Quarzen aus Zerrklüften der Schweizer Alpen. Schweiz Miner Petrol Mitt 41: 335-369
5. Behr HJ (1989) Die geologische Aktivität von Krustenfluiden. Niedersächs Akad Geowiss Veröff H 1: 7-41
6. Behr HJ, Neuser RD, Schmidt-Mumm A, Schneider N (1989) Untersuchungen zur Kathodolumineszenz, Infrarotspektroskopie und Dekripitometrie am Bohrprofil der KTB-Vorbohrung. KTB-Report 89-3: 452
7. Blankenburg H-J, Götze J, Schulz H (1994) Quarzrohstoffe. Dtsch Verl Grundstoffind mbH, Leipzig-Stuttgart, 296 p
8. Bruhn F, Bruckschen P, Meijer J, Stephan A, Richter DK, Veizer J (1996) Cathodoluminescence investigations and trace-element analysis of quartz by micro-PIXE: implications for diagenetic and provenance studies in sandstone. Can Mineral 34: 1223-1232
9. Burley SD, Mullis J, Matter A (1989) Timing diagenesis in the Tartan reservoir (UK North Sea): constraints from cathodoluminescence microscopy and fluid inclusion studies. Mar Petrol Geol 6: 98-120
10. Demars C, Pagel M, Deloule E, Blanc P (1996) Cathodoluminescence of quartz from sandstones: interpretation of the UV range by determination of trace element distributions and fluid-inclusion P-T-X properties in authigenic quartz. Am Mineral 81: 891-901
11. 2. Wiss Z W-Pieck-Univ Rostock, Naturwiss Reihe 32: 27-29
12. Evans J, Hogg AJC, Hopkins MS, Howarth RJ (1994) Quantification of quartz cements using combined SEM, CL, and image analysis. J Sed Res A64: 334-338
13. Flörke OW, Köhler-Herbertz B, Langer K, Tönges F (1982) Water in microcrystalline quartz of volcanic origin: agates. Contrib Mineral Petrol 80: 324-333
14. Frentzel-Beyme K (1989) REM-Kathodolumineszenz-Strukturen im Quarzteilgefüge von Metamorphiten: Bestandsaufnahme und geologische Interpretation. Thesis, University of Göttingen
15. Friebele EJ, Griscom DL, Stapelbroek M, Weeks RA (1979) Fundamental defect centers in glass: the peroxy radical in irradiated, high-purity, fused silica. Phys Rev Lett 42: 1346-1348
16. Füchtbauer H, Leggewie R, Gockeln C, Heinemann C, Schröder P (1982) Methoden der Quarzuntersuchung, angewandt auf mesozoische und pleistozäne Sandsteine und Sande. N Jb Geol Paläont Mh: 193-210
17. Gorobets BS, Gaft ML, Podolskyi AM (1989) Luminescence of minerals and ores (in Russ). Ministery of Geology, Moscow, 53 p
18. Gorton NT, Walker G, Burley SD (1996) Experimental analysis of the composite blue CL emission in quartz. J Lumin 72-74: 669-671
19. Götze J (1996) Kathodolumineszenz von Quarz - Grundlagen und Anwendung in den Geowissenschaften. Aufschluß 47: 145-164
20. Götze J (1998) Geochemistry and provenance of the Altendorf feldspathic sandstone in the Middle Bunter of the Thuringian basin (Germany). Chem Geol 150: 43-61
21. Götze J, Blankenburg H-J (1992) The genesis of the Hohenbocka quartz sand (Eastern Germany) - new results of mineralogical and geochemical investigations. N Jb Geol Paläont Teil I: 1217-1231
22. Götze J, Magnus M (1997) Quantitative determination of mineral abundance in geological samples using combined cathodoluminescence microscopy and image analysis. Eur J Mineral 9: 1207-1215
23. Götze J, Plötze M (1997) Investigation of trace-element distribution in detrital quartz by Electron Paramagnetic Resonance (EPR). Eur J Mineral 9: 529-537
24. Götze J, Rößler R (2000) Kathodolumineszenz-Untersuchungen an Kieselhölzern. I. Silifizierungen aus dem versteinerten Wald von Chemnitz (Perm, Deutschland). Veröff Museum Naturkunde Chemnitz 23: 35-50
25. Götze J, Walther H (1995) A complex mineralogical and geochemical study on a silicified Miocene quartz sand. Zbl Geol Paläont Teil I H 1/2: 119-129
26. Götze J, Zimmerle W (2000) Quartz and silica as guide to provenance in sediments and sedimentary rocks. E Schweizerbart'sche Verlagsbuchhandlung, Stuttgart, 91p (Contrib Sediment Geol 21)
27. Götze J, Höhne D, Do TQ (1993) Genesis and melting behavior of quartz raw materials. Sprechsaal Intern Ceramics & Glass Mag 126: 473-478
28. Götze J, Plötze M, Fuchs H, Habermann D (1999) Defect structure and luminescence behaviour of agate - results of electron paramagnetic resonance (EPR) and cathodoluminescence (CL) studies. Mineral Mag 63: 149-163
29. Griffiths JHE, Owen J, Ward IM (1954) Paramagnetic resonance in neutron-irradiated diamond and smoky quartz. Nature 173: 439-442
30. Griscom DL (1985) Defect structure of glasses: some outstanding questions in regard to vitreous silica. J Non-Cryst Sol 73: 51-77
31. Habermann D, Götze J, Neuser RD, Richter DK (1997) The phenomenon of intrinsic cathodoluminescence: case studies of quartz, calcite and apatite. Zbl Geol Paläont Teil 1 H 10-12: 1275-1284
32. Halliburton LE, Jani MG, Bossoli RB (1984) Electron spin resonance and optical studies of oxygen vacancy centers in quartz. Nucl Instr Meth Phys Res Bl: 192-197
33. Hayes W (1990) The structure of the self-trapped exciton in quartz. Rev Solid State Sci 4: 543-546
34. Houseknecht DW (1991) Use of cathodoluminescence petrography for understanding compaction, quartz cementation, and porosity in sandstones. In: Barker CE, Kopp OC (eds) Luminescence microscopy: quantitative and qualitative aspects. SEPM, Dallas/ Texas, pp 59-66
35. 2. J Phys C, Solid State Phys 21: 4693-4702
36. 2. Phys Rev B27: 2285-2293
37. Jones CE, Embree D (1976) Correlations of the 4.77-4.28 eV luminescence band in silicon dioxide with oxygen vacancy. J Appl Phys 47: 5365-5371
38. Katz S, Halperin A (1988) The low temperature phosphorescence and thermoluminescence of quartz crystals. J Lumin 39: 137-143
39. Kempe U, Götze J, Dandar S, Habermann D (1999) Magmatic and metasomatic processes during formation of the Nb-Zr-REE deposits from Khaldzan Buregte (Mongolian Altai): indications from a combined CL - SEM study. Mineral Mag 63: 165-167
40. Kostov RI, Bershov LV (1987) Systematics of paramagnetic electron-hole centers in natural quartz (in Russ). Izvest AN SSSR, ser geol 7: 80-87
41. Krbetschek MR, Götze J, Dietrich A, Trautmann T (1998) Spectral information from minerals relevant for luminescence dating. Radiat Meas 27: 695-748
42. Lehmann G, Bambauer HU (1973) Quarzkristalle und ihre Farbe. Ang Chemie 85: 281-289
43. Luff BJ, Townsend PD (1990) Cathodoluminescence of synthetic quartz. J Phys Condens Matter 2: 8089-8097
44. Marfunin AS (1979) Spectroscopy, luminescence and radiation centres in minerals. Springer, Berlin Heidelberg New York, 352 p
45. Matter A, Ramseyer K (1985) Cathodoluminescence microscopy as a tool for provenance studies of sandstones. In: Zuffa GG (ed) Provenance of arenites. D Reidel, Boston, pp 191-211 (NATO ASI series C 148)
46. McKeever SWS (1984) Thermoluminescence in quartz and silica. Radiat Prot Dos 8: 81-98
47. Medlin WL (1962) Thermoluminescence in quartz. J Chem Phys 38: 1132-1143
48. Meunier JD, Sellier E, Pagel M (1990) Radiation-damage rims in quartz from uranium-bearing sandstones. J Sed Petrol 60: 53-58
49. Milliken KL, Laubach SE (2000) The role of brittle deformation in sandstone diagenesis and fracture in siliciclastic petroleum reservoirs. In: Pagel M, Barbin V, Blanc Ph, Ohnenstetter D (eds) Cathodoluminescence in geosciences. Springer, Berlin Heidelberg New York Tokyo, pp 225-243
50. Moiseev BM (1985) Natural radiation processes in minerals (in Russ). Nedra, Moscow
51. Morad S, Bhattacharyya A, Al-Aasm IS, Ramseyer K (1991) Diagenesis of quartz in the Upper Proterozoic Kaimur sandstones, Son Valley, central India. Sed Geol 73: 209-225
52. Müller A, Seltmann R, Behr H-J (2000) Application of Cathodoluminescence to magmatic quartz in a tin granite - case study from the Schellerhau granite complex, eastern Erzgebirge, Germany. Mineral Deposita 35: 169-189
53. Nassau K, Prescott BE (1975) A reinterpretation of smoky quartz. Phys Stat Sol 29: 659-663
54. Nettar D, Villafranca JJ (1985) A program for EPR powder spectra simulation. J Magn Res 64: 61
55. Neuser RD, Richter DK, Vollbrecht A (1989) Natural quartz with brown/violet Cathodoluminescence - genetic aspects evident from spectral analysis. Zbl Geol Paläont Teil 1, H 7/8: 919-930
56. Neuser RD, Bruhn F, Götze J, Habermann D, Richter DK (1995) Kathodolumineszenz: Methodik und Anwendung. Zbl Geol Paläont Teil I, H 1/2: 287-306
57. Nutall RHD, Weil JA (1980) Two hydrogenic trapped-hole species in α-quartz. Solid State Comm 33: 99-102
58. Owen MR (1984) Sedimentary petrology and provenance of the upper Jackfork sandstone (Morrowan), Ouachita mountains, Arkansas. Thesis, University of Ilinois, Urbana, 154 p
59. Owen MR (1988) Radiation-damage halos in quartz. Geology 16: 529-532
60. Owen MR (1991) Application of Cathodoluminescence to sandstone provenance. In: Barker CE, Kopp OC (eds) Luminescence microscopy: quantitative and qualitative aspects. SEPM, Dallas/Texas, pp 67-76
61. Owen MR, Anders MH (1988) Evidence from Cathodoluminescence for non-volcanic origin of shocked quartz at the Cretaceous/Tertiary boundary. Nature 334/6178: 145-147
62. Pagel M, Barbin V, Blanc P, Ohnenstetter D (eds) (2000) Cathodoluminescence in geosciences. Springer, Berlin Heidelberg New York Tokyo, 514 p
63. Perny B, Eberhardt P, Ramseyer K. Mullis J, Pankrath R (1992) Microdistribution of Al, Li, and Na in a-quartz: possible causes and correlation with short-lived cathodoluminescence. Am Mineral 77: 534-544
64. Plötze M (1995) EPR-Untersuchungen an Quarz, Scheelit und Fluorit aus hochthermalen Seltenmetallvererzungen. Thesis, TU Bergakademie Freiberg, 141p (unpublished)
65. 0-Zentren. Eur J Mineral 8, Bh 1: 217
66. Pott GT, McNicol BD (1971) Spectroscopic study of the coordination and valence of Fe and Mn ions in and on the surface of aluminas and silicas. Disc Faraday Soc 52: 121-131
67. 1, centers in quartz (in Russ). Dokl AN USSR, ser geol 4: 679-682
68. Ramseyer K, Mullis J (1990) Factors influencing short-lived blue cathodoluminescence of alpha-quartz. Am Mineral 75: 791-800
69. Ramseyer K, Baumann J, Matter A, Mullis J (1988) Cathodoluminescence colours of alpha-quartz. Mineral Mag 52: 669-677
70. Ramseyer K, AlDahan AA, Collini B, Landström O (1992) Petrological modifications in granitic rocks from the Siljan impact structure: evidence from cathodoluminescence. Tectonophysics 216: 195-204
71. Remond G, Cesbron F, Chapoulie R, Ohnensietier D, Roques-Carmes C, Schvoerer M (1992) Cathodoluminescence applied to the microcharacterization of mineral materials: a present status in experimentation and interpretation. Scann Micr 6: 23-68
72. Rink WJ, Rendell H, Marseglia EA, Luff BJ, Townsend PD (1993) Thermoluminescence spectra of igneous quartz and hydrothermal vein quartz. Phys Chem Minerals 20: 353-361
73. Ritter CJ, Dennen WH (1964) Colour center zonation in quartz. Geol Soc Am Bull 75: 915-916
74. Schneider N (1993) Das lumineszenzaktive Strukturinventar von Quarzphänokristen in Rhyolithen. Göttinger Arb Geol Paläont 60: 1-81
75. Serebrennikov AJ, Valter AA, Mashkovtsev RJ, Shcherbakova MYa (1982) The investigation of defects in shock-metamorphosed quartz. Phys Chem Mineral 8: 153-157
76. Seyedolali A, Krinsley DH, Boggs S, O'Hara PF, Dypvik H, Goles GG (1997) Provenance interpretation of quartz by scanning electron microscope-cathodoluminescence fabric analysis. Geology 25: 787-790
77. Siegel GH, Marrone MJ (1981) Photoluminescence in as-drawn and irradiated silica optical fibers: an assessment of the role of nonbridging oxygen defect centres. J Non-Cryst Solids 45: 235-247
78. Sippel RF, Spencer AB (1970) Luminescence petrography and properties of lunar crystalline rocks and breccias. Proc Apollo 11 Lunar Sci Conf, Vol 3: 2413-2426
79. 2 films, and α-quartz. Phys Stat Sol (a) 96: 191-198
80. Sprunt ES, Dengler LA, Sloan D (1978) Effects of metamorphism on quartz cathodoluminescence. Geology 6: 305-308
81. Stevens Kalceff MA, Phillips MR (1995) Cathodoluminescence microcharacterization of the defect structure of quartz. Phys Rev B 52: 3122-3134
82. Stevens Kalceff MA, Phillips MR, Moon AR, Kalceff W (2000) Cathodoluminescence microcharacterization of silicon dioxide polymorphs. In: Pagel M, Barbin V, Blanc P, Ohnenstetter D (eds) Cathodoluminescence in geosciences. Springer, Berlin Heidelberg New York Tokyo, pp 193-224
83. 2. Sov Phys Sol State 21: 644-646
84. Van den Kerkhoff AM, Müller A (1999) Retrograde trace element redistribution in quartz and fluid inclusion modification: observations by cathodoluminescence. Eur J Mineral 11, Bh 1: 121
85. Walker G (1985) Mineralogical applications of luminescence techniques. In: Berry FJ, Vaughan DJ (eds) Chemical bonding and spectroscopy in mineral chemistry. Chapman and Hall, London, pp 103-140
86. 2-Zementen pedogener Silcretes mittels Kathodolumineszenz. Eur J Mineral 5, Bh 1: 55
87. Walther HB, Götze J, Wopfner H (1996) Silica cements in Central Australian silcretes. Intern Conf CL Rel Techn, Nancy, Abstracts, pp 165-166
88. Watt GR, Wright P, Galloway S, McLean C (1997) Cathodoluminescence and trace element zoning in quartz phenocrysts and xenocrysts. Geochim Cosmochim Acta 61: 4337-4348
89. Weil JA (1984) A review of electron spin spectroscopy and its application to the study of paramagnetic defects in crystalline quartz. Phys Chem Minerals 10: 149-165
90. 2 interface 2. Plenum Press, New York, pp 131-144
91. Yang XH, McKeever SWS (1990) Point defects and the pre-dose effect in quartz. Radiat Protect Dosim 33: 27-30
92. Zinkernagel U (1978) Cathodoluminescence of quartz and its application to sandstone petrology. Contrib Sed 8: 1-69