Synthesis and reactivity of a vanadium(III) - Methyl complex stabilized by hexamethylsilazanate ligands

Organometallics

Volumn 15, Issue 25, 1996, Pages 5260-5262

  Gerlach, Christopher P ^a   Arnold, John ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001217718     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960706v     Document Type: Article

References (46)

1. Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987.
2. Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry, 5th ed.; Wiley: New York, 1988.
3. Connelly, N. G. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Oxford, U.K., 1981; Vol. 3, p 647.
4. Nieman, J.; Scholtens, H.; Teuben, J. H. J. Organomet. Chem. 1980, 186, C12.
5. Nieman, J.; Teuben, J. H.; Huffman, J. C.; Caulton, K. G. J. Organomet. Chem. 1983, 255, 193.
6. Seidel, W.; Kreisel, G. Z. Chem. 1974, 14, 25.
7. Gambarotta, S.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. J. Chem. Soc., Chem. Commun. 1984, 886.
8. For studies of hydrocarbyl derivatives of the CpV(III) fragment, see the following and references therein: Buijink, J.-K.; Kloetstra, K. R.; Meetsma, A.; Teuben, J. H. Organometallics 1996, 15, 2523.
9. 3(THF) see the following and references therein: (a) Vivanco, M.; Ruiz, J.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1794. (b) Vivanco, M.; Ruiz, J.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1802. (c) Ruiz, J.; Vivanco, M.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1811.
10. 3(THF) see the following and references therein: (a) Vivanco, M.; Ruiz, J.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1794. (b) Vivanco, M.; Ruiz, J.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1802. (c) Ruiz, J.; Vivanco, M.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1811.
11. 3(THF) see the following and references therein: (a) Vivanco, M.; Ruiz, J.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1794. (b) Vivanco, M.; Ruiz, J.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1802. (c) Ruiz, J.; Vivanco, M.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1993, 12, 1811.
12. Buijink, J.-K.; Meetsma, A.; Teuben, J. H. Organometallics 1993, 72, 2004.
13. Song, J.-I.; Berno, P.; Gambarotta, S. J. Am. Chem. Soc. 1994, 116, 6927.
14. Berno, P.; Minhas, R.; Hao, S.; Gambarotta, S. Organometallics 1994, 13, 1052.
15. w = 0.0441.
16. The covalent convention is followed in counting electrons. See: Crabtree, R. H. The Organometallic Chemistry of the Elements, 2nd ed.; Wiley: New York, 1994.
17. Berno, P.; Gambarotta, S. J. Chem. Soc., Chem Commun. 1994, 2419.
18. Berno, P.; Gambarotta, S. Organometallics 1994, 13, 2569.
19. Berno, P.; Gambarotta, S. Angew. Chem., Int. Ed. Engl. 1995, 34, 822.
20. Morris, R. J.; Wilson, S. R.; Girolami, G. S. J. Organomet. Chem. 1994, 480, 1.
21. Protasiewicz, J. D.; Bianconi, P. A.; Williams, I. D.; Liu, S.; Rao, C. P.; Lippard, S. J. Inorg. Chem. 1992, 31, 4134.
22. Hessen, B.; Teuben, J. H.; Lemmen, T. H.; Huffman, J. C.; Caulton, K. G. Organometallics 1985, 4, 946.
23. Hessen, B.; Lemmen, T. H.; Luttikhedde, H. J. G.; Teuben, J. H.; Petersen, J. L.; Huffman, J. C.; Jagner, S.; Caulton, K. G. Organometallics 1987, 6, 2354.
24. Buijink, J.-K. F.; Meetsma, A.; Teuben, J. H.; Kooijman, H.; Spek, A. L. J. Organomet. Chem. 1995, 497, 161.
25. de With, J.; Horton, A. D.; Orpen, A. G. Organometallics 1990, 8, 2207.
26. -1, T = 168 K. Data were collected and the structure refined as for 1. The final residuals for 414 variables refined against 3018 data for which I > 3σ(I) were R = 0.0432 and , = 0.0518.
27. Barker, M. W.; McHenry, W. E. In The Chemistry of Ketenes, Allenes and Related Compounds; Patai, S., Ed.; Wiley: Chichester, U.K., 1980; p 701.
28. Clark, J. R.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Chem. Commun. 1993, 1233.
29. Clark, J. R.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1996, 15, 3232.
30. Radu, N. S.; Engeler, M. P.; Gerlach, C. P.; Tilley, T. D. J. Am. Chem. Soc. 1996, 117, 3621.
31. Moloy, K. G.; Fagan, P. J.; Manriquez, J. M.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 56.
32. Chandrasekhar, P.; Bird, P. H. Inorg. Chem. 1984, 23, 3677.
33. Money J. K.; Folting, K.; Huffman, J. C.; Christou, G. Inorg. Chem. 1987, 26, 944.
34. Knopp, P.; Wieghardt, K.; Nuber, B.; Weiss, J.; Sheldrick, W. S. Inorg. Chem. 1990, 29, 363.
35. Brand, S. G.; Edelstein, N.; Hawkins, C. J.; Shalimoff, G.; Snow, M. R.; Tiekink, E. R. T. Inorg. Chem. 1990, 29, 434.
36. Zhang, Y.; Holm, R. H. Inorg. Chem. 1990, 29, 911.
37. Ruiz, J.; Vivanco, M.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. J. Chem. Soc., Chem. Commun. 1991, 762.
38. Wanandi, P. W.; Davis, W. B.; Cummins, C. C. J. Am. Chem. Soc. 1995, 117, 2110.
39. -1.
40. w = 0.0259.
41. 6): δ 0.96, 0.64, 0.39, 0.21, -1.2.
42. Bennett, C. R.; Bradley, D. C. J. Chem. Soc., Chem. Commun. 1974, 29.
43. Simpson, S. J.; Andersen, R. A. Inorg. Chem. 1981, 20, 3627.
44. Planalp, R. P.; Andersen, R. A.; Zalkin, A. Organometallics 1983, 2, 16.
45. Simpson, S. J.; Turner, H. W.; Andersen, R. A. J. Am. Chem. Soc. 1979, 101, 7728.
46. Simpson, S. J.; Turner, H. W.; Andersen, R. A. Inorg. Chem. 1981, 20, 2991.