Pressure dependence of metal-catalyzed polymerization in the gas phase. A study of radiative and collisional relaxation

Journal of Physical Chemistry

Volumn 100, Issue 37, 1996, Pages 15118-15123

  Bjarnason, Asgeir ^a   Ridge, D P ^b  

^a UNIVERSITY OF ICELAND   (Iceland)

^b UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001211609     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp953768s     Document Type: Article

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33. A reviewer has properly pointed out that the excited state of the reactant ion might originally have distribution of vibrationally excited states, and thus we would be dealing with a distribution of rate constants. Incorporation of this possibility would, however, make the kinetic analysis hopelessly complex. The rate constants derived in this study, thus, represent an average behavior of the distribution mentioned above.
34. 0) must have been significantly less than the above stated 10%.