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This subtraction must be done point by point, but as the discrete pressure for the baseline measurement did not match the discrete pressure for ice Ih or HDA measurements, smooth lines were drawn through the data point and the smoothed data were subtracted to obtain a smooth line. The procedure hides the scatter in the experimental values, but it is an accepted practice when the number of data points is large. For that reason, earlier studies (Refs. 5, 7, 28) also had provided only smooth lines for the piston displacement pressure data.
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In the earlier studies (Refs. 5, 6, 8, 9, 17, 31, 32) 3-4 cm thick plates of a high density, polymer-glass fiber composite material was used for thermal isolation. These plates deform more on the initial loading, and recover equally more on the final unloading. This produces an upwards curvature in the displacement curves in the 1 bar-3 kbar range of both the compression and decompression parts of a pressure cycle. The effect is more on decompression of HDA below 3-4 kbar, because a relatively large recovery of the plate's thickness adds to the small recovery of the volume of HDA. This appears to distort the shape of the piston displacement against pressure plot for HDA more than for ice Ih (Refs. 5, 6, 8, 9, 17, 28). As the plots are almost equally curved on compression of ice Ih and decompression of HDA, the difference is small for the volume, and more for the compressibility.
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