Photoreaction of 1-(o-Allyloxyphenyl)-2-pentamethyldisilanylethyne with Methanol or Acetone

Bulletin of the Korean Chemical Society

Volumn 19, Issue 6, 1998, Pages 686-689

  Shim, Sang Chul ^a   Park, Seung Ki ^b  

^a Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

^b Suwon University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001203595     PISSN: 02532964     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (15)

1. (a) Ishikawa, M.; Fuckikami, T.; Kumada, M. J. Chem. Soc., Chem. Commun. 1977, 352.
2. (b) Ishikawa, M.; Nishimura, K.; Sugisawa, H.; Kumada, M. J. Organomet. Chem. 1980, 194, 147.
3. Seyferth, D.; Vick, S. C.; Shannon, M. L. Organometallics 1984, 31, 1897.
4. (a) Kwon, J. H.; Lee, S. T.; Hoshino, M.; Shim, S. C. J. Org. Chem. 1994, 59, 1108.
5. (b) Shim, S. C.; Lee, S. T. J. Chem. Soc., Perkin Trans. 2 1994, 1979.
6. Shim, S. C.; Lee, S. T. Bull. Korean Chem. Soc. 1995, 16(10), 988.
7. Lee, S. T.; Baek, E. K.; Shim, S. C. Organometallics 1996, 15, 2182.
8. (a) Conlin, R. T.; Gasper, P. P. J. Am. Chem. Soc. 1976, 98, 3715.
9. (b) Belzner, J.; Ihmels, H. Tetrahedron Lett. 1993, 34, 6541.
10. Shim, S. C.; Park, S. K. The results in the absence of trapping agents are submitted for publication.
11. Ishikawa, M.; Fuchikami, T.; Kumada, M. J. Am. Chem. Soc. 1977, 99, 245.
12. Shizuka, H.; Okazaki, K.; Tanaka, H.; Tanaka, M.; Ishikawa, M.; Sumitani, M.; Yoshihara, K. J. Phy. Chem. 1987, 91, 2057.
13. Ishikawa, M.; Sugisawa, H.; Fuchikami, Y.; Kumada, M.; Ymabe, T.; Kawakami, H.; Fukui, K.; Uek, Y.; Shizuka, H. J. Am. Chem. Soc. 1982,104, 2872.
14. (a) Clerc, P.; Simon, S. Tables of Spectral Data for Structure Determination of Organic Compounds; Springer-Verlag: New York and London, 1983.
15. (b) Carbon 13 NMR Shift Prediction Module; ChemWindow software program, Softshell international, Ltd., 715 Horizon Drive, Grand Junction, CO 81506. The chemical shifts for the ethynyl carbons of (2) and (8) appear at (δ 97.49, 103.30) and (δ 97.9, 103.7). respectively. From this results, it is thought that the C(1)-C(2) triple bond of (2) remains intact in this photoreaction.