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Volumn 61, Issue 11, 1996, Pages 3687-3693

Asymmetric synthesis of α-amino phosphonic acids by diastereoselective addition of trimethyl phosphite onto chiral oxazolidines

(4) Maury, Catherine a Gharbaoui, Tawfik a Royer, Jacques a Husson, Henri Philippe a

a CNRS (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001195570 PISSN: 00223263 EISSN: None Source Type: Journal
DOI: 10.1021/jo960020c Document Type: Article

Times cited : (59)

References (47)

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- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
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6
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- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1995) J. Org. Chem. , vol.60 , pp. 6656-6657
- Sasai, H.¹ Arai, S.² Tahara, Y.³ Shibasaki, M.⁴

7
- 0029025424
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1995) Tetrahedron Lett. , vol.36 , pp. 4451-4454
- Hamilton, R.¹ Walker, B.² Walker, B.J.³

8
- 0028878264
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1995) Tetrahedron , vol.51 , pp. 1817-1826
- Cabella, G.¹ Jommi, G.² Pagliarin, R.³ Sello, G.⁴ Sisti, M.⁵

9
- 0027949155
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1994) Tetrahedron Lett. , vol.35 , pp. 8045-8048
- Bongini, A.¹ Camerini, R.² Hofman, S.³ Panunzio, M.⁴

10
- 0028072874
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1994) J. Am. Chem. Soc. , vol.116 , pp. 9377-9378
- Yager, K.M.¹ Taylor, C.M.² Smith III, A.B.³

11
- 0028027606
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1994) J. Org. Chem. , vol.59 , pp. 5784-5793
- Song, Y.¹ Niederer, D.² Lane-Bell, P.M.³ Lam, L.K.P.⁴ Crawley, S.⁵ Palcic, M.M.⁶ Pickard, M.A.⁷ Pruess, D.L.⁸ Vederas, J.C.⁹

12
- 0028618170
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1994) Synthesis , pp. 1272-1274
- Hanessian, S.¹ Bennani, Y.L.²

13
- 0028019445
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1994) Tetrahedron: Asymm. , vol.5 , pp. 1965-1972
- Gajda, T.¹

14
- 84986675564
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1993) Liebigs Ann. Chem. , pp. 427-431
- Groth, U.¹ Lehmann, L.² Richter, L.³ Schöllkopf, U.⁴

15
- 27844536987
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1993) Russ. Chem. Rev. , vol.62 , pp. 261-278
- Kukhar, V.P.¹ Svistunova, N.Y.² Solodenko, V.A.³ Soloshonok, V.A.⁴

16
- 0001750272
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1993) Phosphorus, Sulfur Silicon , vol.81 , pp. 83-87
- Jacquier, R.¹ Lhassani, M.² Petrus, C.³ Petrus, F.⁴

17
- 85060044559
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1993) Synlett , pp. 35-36
- Hanessian, S.¹ Bennani, Y.L.² Hervé, Y.³

18
- 0026673930
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1992) Tetrahedron , vol.48 , pp. 7275-7288
- Jommi, G.¹ Miglierini, G.² Pagliarin, R.³ Sello, G.⁴ Sisti, M.⁵

19
- 0026579172
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1992) Tetrahedron , vol.48 , pp. 2191-2208
- Denmark, S.E.¹ Chatani, N.² Pansare, S.V.³

20
- 0026619118
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1992) Synthesis , pp. 1226-1228
- Dumy, P.¹ Escale, R.² Girard, J.-P.³ Parello, J.⁴ Vidal, J.-P.⁵

21
- 84986703982
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1992) Liebigs Ann. Chem. , pp. 903-909
- Groth, U.¹ Richter, L.² Schöllkopf, U.³

22
- 0026551174
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1992) Tetrahedron: Asymm. , vol.3 , pp. 377-378
- Yokomatsu, T.¹ Shibuya, S.²

23
- 0026543978
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1992) Tetrahedron , vol.48 , pp. 117-122
- Groth, U.¹ Richter, L.² Schöllkopf, U.³

24
- 0026549026
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1992) Synthesis , pp. 90-95
- Laschat, S.¹ Kunz, H.²

25
- 0025779473
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1991) Tetrahedron: Asymm. , vol.36 , pp. 913-917
- Ouazzani, F.¹ Roumestant, M.-L.² Viallefont, P.³ El Hallaoui, A.⁴

26
- 0025187520
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1990) Tetrahedron Lett. , vol.31 , pp. 6465-6468
- Hanessian, S.¹ Bennani, Y.L.²

27
- 84986691327
- For recently reported asymmetric syntheses see: (a) Smith, A. B., III; Yager, K. M.; Taylor, C. M. J. Am. Chem. Soc., 1995, 117, 10879-10888;. (b) Sasai, H.; Arai, S.; Tahara, Y.; Shibasaki, M. J. Org. Chem. 1995, 60, 6656-6657. (c) Hamilton, R.; Walker, B.; Walker, B. J. Tetrahedron Lett. 1995, 36, 4451-4454. (d) Cabella, G.; Jommi, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1995, 51, 1817-1826. (e) Bongini, A.; Camerini, R.; Hofman, S.; Panunzio, M. Tetrahedron Lett. 1994, 35, 8045-8048. (f) Yager, K. M.; Taylor, C. M.; Smith, A. B., III. J. Am. Chem. Soc. 1994, 116, 9377-9378. (g) Song, Y.; Niederer, D.; Lane-Bell, P. M.; Lam, L. K. P.; Crawley, S.; Palcic, M. M.; Pickard, M. A.; Pruess, D. L.; Vederas, J. C. J. Org. Chem. 1994, 59, 5784-5793. (h) Hanessian, S.; Bennani, Y. L. Synthesis 1994, 1272-1274. (i) Gajda, T. Tetrahedron: Asymm. 1994, 5, 1965-1972. (j) Groth, U.; Lehmann, L.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1993, 427-431. (k) Kukhar, V. P.; Svistunova, N. Y.; Solodenko, V. A.; Soloshonok, V. A. Russ. Chem. Rev. 1993, 62, 261-278. (l) Jacquier, R.; Lhassani, M.; Petrus, C.; Petrus, F. Phosphorus, Sulfur Silicon 1993, 81, 83-87. (m) Hanessian, S.; Bennani, Y. L.; Hervé, Y. Synlett 1993, 35-36. (n) Jommi, G.; Miglierini, G.; Pagliarin, R.; Sello, G.; Sisti, M. Tetrahedron 1992, 48, 7275-7288. (o) Denmark, S. E.; Chatani, N.; Pansare, S. V. Tetrahedron 1992, 48, 2191-2208. (p) Dumy, P.; Escale, R.; Girard, J.-P.; Parello, J.; Vidal, J.-P. Synthesis 1992, 1226-1228. (q) Groth, U.; Richter, L.; Schöllkopf, U. Liebigs Ann. Chem. 1992, 903-909. (r) Yokomatsu, T.; Shibuya, S. Tetrahedron: Asymm. 1992, 3, 377-378. (s) Groth, U.; Richter, L.; Schöllkopf, U. Tetrahedron 1992, 48, 117-122. (t) Laschat, S.; Kunz, H. Synthesis 1992, 90-95. (u) Ouazzani, F.; Roumestant, M.-L.; Viallefont, P.; El Hallaoui, A. Tetrahedron: Asymm. 1991, 36, 913-917. (v) Hanessian, S.; Bennani, Y. L. Tetrahedron Lett. 1990, 31, 6465-6468. (w) Sting, M.; Steglich, W. Synthesis 1990, 132-134.
- (1990) Synthesis , pp. 132-134
- Sting, M.¹ Steglich, W.²

28
- 0026663281
- Maury, C.; Royer, J.; Husson, H.-P. Tetrahedron Lett. 1992, 33, 6127-6130.
- (1992) Tetrahedron Lett. , vol.33 , pp. 6127-6130
- Maury, C.¹ Royer, J.² Husson, H.-P.³

29
- 0000051858
- The conception of this compound was inspired by the asymmetric synthesis of carboxylic acids described some years ago: (a) Dellaria, J. F.; Santarsiero, B. D. J. Org. Chem. 1989, 54, 3916-3926. (b) Sinclair, P. J.; Zhai, D.; Reibenspies, J.; Williams, R. M. Tetrahedron Lett. 1988, 29, 6075-6078.
- (1989) J. Org. Chem. , vol.54 , pp. 3916-3926
- Dellaria, J.F.¹ Santarsiero, B.D.²

30
- 0000677999
- The conception of this compound was inspired by the asymmetric synthesis of carboxylic acids described some years ago: (a) Dellaria, J. F.; Santarsiero, B. D. J. Org. Chem. 1989, 54, 3916-3926. (b) Sinclair, P. J.; Zhai, D.; Reibenspies, J.; Williams, R. M. Tetrahedron Lett. 1988, 29, 6075-6078.
- (1988) Tetrahedron Lett. , vol.29 , pp. 6075-6078
- Sinclair, P.J.¹ Zhai, D.² Reibenspies, J.³ Williams, R.M.⁴

31
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- (a) Wu, M. J.; Pridgen, L. N. J. Org. Chem. 1991, 56, 1340-1344.
- (1991) J. Org. Chem. , vol.56 , pp. 1340-1344
- Wu, M.J.¹ Pridgen, L.N.²

32
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