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Volumn 20, Issue 19, 1979, Pages 1665-1668

E- and Z-vinyloxyboranes (alkenyl borinates): stereoselective formation and aldol condensation

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EID: 0001191080     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(01)93618-4     Document Type: Article
Times cited : (91)

References (20)
  • 6
    • 0038405548 scopus 로고
    • 7 in 1 and 2) by direct distillation of the reaction intermediate. Heat and possibly moisture (inadvertently contaminated) might have caused partial isomerization of the originally formed E-isomer to the other.
    • (1970) Tetrahedron Lett. , pp. 215
    • Pasto1    Wojtowski2
  • 10
    • 33947300463 scopus 로고
    • Reaction of organoboranes with diazo esters and diazo ketones in the presence of deuterium oxide. A New synthesis of .alpha.-deuterio- and .alpha., .alpha.-dideuterio esters and ketones
    • (1969) Journal of the American Chemical Society , vol.91 , pp. 6195
    • Hooz1    Gunn2
  • 13
    • 84918339886 scopus 로고    scopus 로고
    • R. Köster, et al., earlier showed that the Z-isomer of a vinyloxyborane undergoes a stereoselective aldol condensation in two instances.
  • 14
    • 84918339885 scopus 로고    scopus 로고
    • The isomerization of E- to Z-vinyloxyborane could also be readily effected with catalytic amounts (0.02 equiv) of lithium t-butoxide or even with water in some cases.
  • 16
    • 84918339884 scopus 로고    scopus 로고
    • 4 to give a diastereoisomeric mixture of the diols. NMR spectra of the isopropylidine derivatives of the diols are also consistent with the assignments shown in Table 3.
  • 17
    • 84918339883 scopus 로고    scopus 로고
    • 3) of C(3)-H of 6 or 7: 6a, δ 4.70 (d, J=8.7 Hz); 6b, δ 4.68 (d, J=7.4 Hz); 6c, δ 4.92 (d, J=7.5 Hz); 7a, δ 4.78 (d, J=6.8 Hz); 7b, δ 4.66 (d, J=6.5 Hz); 7c, δ 4.97 (d, J=5.5 Hz); 7d, δ 3.54 (ddd, J=4.7, 4.8, 8.2 Hz); 7e, δ 3.52 (dd, J=4.4, 6.5 Hz).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.