Bis(1-3:5-6-η-cyclooctadienyl)ruthenium: Preparation, NMR spectroscopy, and isomerization to (η6-1,3,5-cyclooctatriene)(1-2:5-6-η-1,5-cyclooctadiene)ruthenium via the activation of a CH bond

Journal of Organometallic Chemistry

Volumn 272, Issue 2, 1984, Pages 179-188

  Itoh, Kenji ^a   Nagashima, Hideo ^a   Ohshima, Toshiyuki ^a   Oshima, Noriaki ^a   Nishiyama, Hisao ^a  

^a TOYOHASHI UNIVERSITY OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001182590     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(84)80465-9     Document Type: Article

References (34)

1. Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H)
2. Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups
3. Activation of methane by iridium complexes
4. Iridium complexes in alkane dehydrogenation
5. ?-Arene complexes as unexpected deactivation products in alkane activation and alkene hydrogenation reactions
6. Novel ruthenium(II) olefin complex with a coordinated alicyclic carbon-hydrogen bond.
7. Metall-π-Komplexe des Rutheniums und Osmiums mit 6-und 8-gliedrigen cyclischen Oligoolefinen
8. Neue π-komplexe des eisen(o) und ruthenium(o) mit cyclischen oligoolefinen
9. Selective (.PI.6s+.PI.2s) cycloaddition of a coordinated cyclic triene with alkynes. Formation of bicyclo(4.2.2)decatriene skeleton on a Ru(0) template.