Molecular design of new chromophores for high performance poled polymers

Progress in Natural Science

Volumn 10, Issue 4, 2000, Pages 252-258

  Wang, Peng ^a   Zhu, Peiwang ^a   Wu, Wei ^a   Ye, Cheng ^a  

^a INSTITUTE OF CHEMISTRY   (China)

Author keywords

AM1 Finite Field; Molecular design; Poled polymer

Indexed keywords

ECONOMIC AND SOCIAL EFFECTS; GLASS TRANSITION; NONLINEAR OPTICS; THERMAL ENGINEERING;

AM1/FINITE FIELD; FINITE FIELDS; MOLECULAR DESIGN; MOLECULAR ENGINEERING; NON-LINEAR OPTICAL ACTIVITY; NONLINEAR OPTICAL PROPERTIES; PERFORMANCE; POLED POLYMER; SECOND-ORDER NONLINEAR OPTICAL; TRADE OFF;

CHROMOPHORES;

EID: 0001178234     PISSN: 10020071     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (16)

1. Prasad, N. P., Williams, D. J., Introduction to Nonlinear Optical Effects In Molecules and Polymers, New York: John Wiley & Sons, 1991.
2. Dalton, L. R., Harper, A. W., Wu, B. et al., Polymeric electro-optic modulators: material synthesis and processing, Adv. Mater., 1995, 7: 519.
3. Dagani, R., Devices based on electrooptic polymers begin to enter marketplace, C&EN, 1996, 74(10): 22.
4. Zyss, J., Ledoux, I., Nicoud, J. F., in Molecular Nonlinear Optics: Materials, Physics and Devices (ed. by Zyss, J.), Boston: Academic Press, Inc., 1994, Ch. 4, 132-153.
5. Wang, C.G., Wang, P., Zhu, P. W. et al., Synthesis of diamino-substituted nitrogen heterocyclic NLO chromophores and their second order nonlinearities, Progress in Natural Science, 1998, 8(4): 498.
6. Stahelin, M., Burland, D. M., Rice, J. E., Solvent dependence of the second order hyperpolarizability in p-nitroaniline, Chem. Phys. Lett., 1992, 191(3,4): 245.
7. Dirk, C. W., Katz, H. E., Schilling, M. L., Use of thiazole rings to enhance molecular second-order nonlinear optical susceptibility, Chem. Mater., 1990, 2: 700.
8. Ye, C., Some problems for practicality of nonlinear optical polymers, in 100 Scientific Puzzles of the 21st Century, Changchun: Jilin' People Publishing House, 1998, 262-274.
9. Harper, A. W., Dalton, L. R., Garner, S. M. et al., Translating microscopic optical nonlinearity into macroscopic optical nonlinearity: the role of chromophore-chromophore electrostatic interactions, J. Opt. Soc. Am. B, 1998, 15: 329.
10. Marder, S. R., Cheng, L. T., Tiemann, B. G. et al., Large first hyperpolarizabilities in push-pull polyenes by tuning of the bond length alternation and aromaticity, Science, 1994, 263: 511.
11. Albert, I. D. L., Marks, T. J., Ratner, M. A., Large molecular hyperpolarizabilities in "push-pull" porphyrins, Molecular planarity and auxiliary donor-acceptor effects, Chem. Mater., 1998, 10: 753.
12. Wang, P., Zhu, P. W., Wang, C. G. et al., Theoretical investigation and molecular design of pyrazine derivatives with large hyperpolarizabilities(β), J. Mol. Struct. (THEOCHEM), 1999, 459: 155.
13. Ikeda, H., Sakai, T., Kawasaki, K., Nonlinear optical properties of cyanine dyes, Chem. Phys. Lett., 1991, 179: 551.
14. Wong, M. S., Bosshard, C., Pan, F. et al., Non-classical donor-acceptor chromophores for second order nonlinear optics, Adv. Mater., 1996, 8: 677.
15. Wang, P., Zhu, P. W., Wu, W. et al., Design of novel chromophores with multiple substitutions, Phys. Chem. Chem. Phys., 1999, 1: 3519.
16. Nalwa, H. S., Watanabe, T., Miyata, S., 2-D charge transfer molecules for second-order NLO: off diagonal orientation, Adv. Mater., 1995, 7(8): 754.