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The chemical shift change due to the 1:1 complex formation could not be estimated here, since the spectrum for the free anion of DPP is not available at present. The specimen for the free DPP used here was prepared from acidic solutions, and DPP therein is protonated. Thus, we focus the present analysis to the comparison of the spectral change of DPP on the complex formation with the Ce(IV) ion with the corresponding values for other lanthanide ions
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The chemical shift change due to the 1:1 complex formation could not be estimated here, since the spectrum for the free anion of DPP is not available at present. The specimen for the free DPP used here was prepared from acidic solutions, and DPP therein is protonated. Thus, we focus the present analysis to the comparison of the spectral change of DPP on the complex formation with the Ce(IV) ion with the corresponding values for other lanthanide ions.
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