Trisilyloxonium Ions: Preparation, NMR Spectroscopy, ab Initio/IGLO Studies, and Their Role in Cationic Polymerization of Cyclosiloxanes

Journal of the American Chemical Society

Volumn 117, Issue 35, 1995, Pages 8962-8966

  Olah, George A ^a   Li, Xing Ya ^a   Wang, Qunjie ^a   Rasul, Golam ^a   Surya Prakash, G K ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001164437     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00140a010     Document Type: Article

References (40)

1. Olah, G.A.; Rasul, G.; Aniszfeld, R.; Prakash, G.K.S. J. Am. Chem. Soc. 1992, 114, 5608.
2. Cypryk, M.; Chonjnowski, J. Macromolecules 1991, 24, 2498.
3. Wilczek, L.; Rubinsztajn, S.; Chonjnowski, J. Makromol. Chem. 1986, 187, 39.
4. Chonjnowski, J.; Rubinsztajn, S.; Wilczek, L. L‘actualite’ Chim. 1986, 3, 56.
5. Sigwalt, P.; Gobin, C.; Nicol, P.; Moreau, M.; Masure, M. Polym. Prepr. 1990, 31, 40.
6. Sigwalt, P. Polym. J. 1987, 19, (5), 567.
7. Sigwalt, P. L‘actualite’ Chim. 1986, 3, 45.
8. Sauvet, G.; Lebrun, J.J.; Sigwalt, P. In Cationic Polymerization and Related Processes; Goethals, E.J., Ed.; Academic Press: New York, NY, 1984; p 237.
9. Kendrick, T.C. J. Chem. Soc. 1965, 2027.
10. Olah, G.A.; Doggweiler, H.; Felberg, J.D.; Frohlich, S. J. Org. Chem. 1985, 50, 4847.
11. Corey, J.Y. J. Am. Chem. Soc. 1975, 97, 3237.
12. Corey, J.Y.; West, R. J. Am. Chem. Soc. 1963, 85, 2430.
13. Kira, M.; Hino, T.; Sakurai, H. J. Am. Chem. Soc. 1992, 114, 6697.
14. Bahr, S.R.; Boudjouk, P. J. Am. Chem. Soc. 1993, 115, 4514.
15. Lambert, J.B.; Zhang, S.; Ciro, S.M. Organometallies 1994, 13, 2430.
16. Lambert, J.B.; Zhang, S.; Stern, C.L.; Huffman, J.L. Science 1993, 260, 1917.
17. Olah, G.A.; Rusul, G.; Li, X.-Y.; Buchholz, H.A.; Sandford, G.; Prakash, G.K.S. Science 1994, 263, 983.
18. Olah, G.A.; Wang, Q.-J.; Prakash, G.K.S. Unpublished.
19. Olah, G.A.; Rasul, G.; Buchholz, H.; Li, X.-Y.; Prakash, G.K.S. Bull. Soc. Chim. Fr., in press.
20. Xie, Z.; Bau, R.; Reed, C.A. J. Chem. Soc., Chem. Commun. 1994, 2519.
21. Olah, G.A.; Rasul, G.; Heiliger, L.; Bausch, J.; Prakash, G.K.S. J. Am. Chem. Soc. 1992, 114, 7737.
22. Prakash, G.K.S.; Reddy, V.P.; Rasul, G.; Casanova, J.; Olah, G.A. J. Am. Chem. Soc. 1992, 114, 3076.
23. Nishida, H.; Takada, N.; Yoshimura, M.; Sonoda, T.; Kobayash, H. Bull. Chem. Soc. Jpn. 1984, 57, 2600.
24. Massay, A.G., Park, A.J. J. Organomet. Chem. 1964, 2, 245.
25. Chien, J.C.W.; Tsai, W.-M.; Ransch, M.D. J. Am. Chem. Soc. 1991, 113, 8570.
26. Frisch, M.J.; Trucks, G.W.; Head-Gordon, M.; Gill, P.M.W.; Wong, M.W.; Foresman, J.B.; Johnson, B.G.; Schlegel, H.B.; Robb, M.A.; Replogle, E.S.; Gomperts, R.; Andres, J.L.; Raghavachari, K.; Binkley, J.S.; Gonzalez, C.; Martin, R.L.; Fox, D.J.; Defrees, D.J.; Baker, J.; Stewart, J.J.P.; Pople, J.A. Gaussian 92, Revision B; Gaussian, Inc.: Pittsburgh, PA, 1992.
27. Here, W.J.; Radom, L.; Schleyer, P.R.; Pople, J.A. Ab Initio Molecular Orbital Theory; Wiley-Interscience: New York, 1986; p 226.
28. Schindler, M. J. Am. Chem. Soc. 1987, 109, 1020.
29. Huzinaga, S. Approximate Atomic Wave Function; University of Alberta: Edmonton, Alberta, 1971.
30. Chuit, C.; Corriu, R.J.P.; Reye, C.; Young, J.C. Chem. Rev. 1993, 93, 1371.
31. Corriu, R.; Guerin, C.; Moreau, J. In The Chemistry of Organosilicon Compounds; Patai, S., Rapporport, Z., Eds.; Wiley: Chichester, U.K., 1989; p 305.
32. Holmes, R.R. Chem. Rev. 1990, 90, 17.
33. Hatanaka, Y.; Hiyama, T. J. Org. Chem. 1989, 54, 268.
34. Sakurai, H. Synlett 1989, 1, 1.
35. Yamamoto, Y.; Takeda, Y.; Akiba, K. Tetrahedron Lett. 1989, 30, 725.
36. Aiube, Z.H.; Eaborn, C. J. Organomet. Chem. 1991, 421, 159.
37. Eaborn, C.; Saxena, A. J. Chem. Soc., Perkin Trans. 2 1987, (6), 779.
38. Hartz, N.; Rasul, G.; Olah, G.A. J. Am. Chem. Soc. 1993, 115, 1277.
39. Sheldrick, W.S. In The Chemistry of Organic Silicon Compounds; Patai, S., Rapporport, Z., Eds.; Wiley: Chichester, U.K., 1989: p 262.
40. Hrkach, J.S.; Matyjaszewski, K. Macromolecules 1990, 23, 4042.