Synthesis and reactions of trigonal-bipyramidal rhenium and technetium complexes with a tripodal, tetradentate NS3 ligand

Inorganica Chimica Acta

Volumn 240, Issue 1-2, 1995, Pages 465-478

  Spies, Hartmut ^a   Glaser, Matthias ^a   Pietzsch, Hans Jürgen ^a   Hahn, F Ekkehardt ^b   Lügger, Thomas ^b  

^a INSTITUTE OF ION BEAM PHYSICS AND MATERIALS RESEARCH   (Germany)

^b FREIE UNIVERSITÄT BERLIN   (Germany)

Author keywords

Crystal structures; Isocyanide complexes; Rhenium complexes; Technetium complexes; Trigonal bipyramidal complexes

Indexed keywords

EID: 0001162713     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/0020-1693(95)04571-6     Document Type: Article

References (39)

1. Rhenium complexes with di- and tri-thiolate ligands. The synthesis and X-ray crystal structures of square pyramidal [PPh4][ReO(SCH2CH2S)2] and [NMe4][ReS(SCH2CH2S)2] and trigonal prismatic [PPh4][Re{(SCH2)3CCH3}2]
2. Isocyanide Synthesis with Phosphoryl Chloride and Diisopropylamine
3. 788. Complex compounds of tertiary phosphines and a tertiary arsine with rhenium(V), rhenium(III), and rhenium(II)
4. The preparation and reactions of trihaolgeno(alkanonitrile)bis(triphenylphosphine)rhenium(III) complexes
5. Die Kristall- und Molekülstruktur von Bis(trimethylsilyl)diimin
6. An empirical method for correcting diffractometer data for absorption effects
7. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
8. Chemistry of low-valent metal isocyanide complexes. Part 1. Synthesis of zerovalent iron and ruthenium complexes. Crystal and molecular structures of tetrakis(t-butyl isocyanide)(triphenylphosphine)ruthenium and pentakis(t-butyl isocyanide)iron
9. Nuclear magnetic resonance spectra of d 4-complexes of rhenium(III) and osmium(IV) with phosphine and arsine ligands
10. Magnetic susceptibilities of some rhenium(III) and osmium(IV) halide complexes; preparation of some new d 4 complexes
11. �ber Die Hydrazin-Carbylamin-Komplexe des Platins
12. Isonitrile complexes of osmium and their reactions to give hydride, amine, and carbene complexes
13. Nucleophilic attack at co-ordinated isocyanides promoted by the 2-pyridyl ligand
14. Preparation of the isocyanide complexes trans-[ReCl(CNR)(dppe)2](R = Me or But) and their reactions with acid to give carbyne complexes. X-Ray crystal structure of trans-[ReCl(CNHMe)(dppe)2][BF4]
15. Protonation of isonitriles ligating molybdenum(0) and tungsten(0) at nitrogen giving complexes of carbyne and carbene ligands
16. Formation of carbyne-like ligands by the protonation of isonitriles ligating electron-rich metal centres; X-ray structure of trans-[Mo(CNMe)2(Ph2PCH2CH2PPh2)]
17. Reactions of [Fe2(?-dienyl)2(CO)4?n (CNR) n ] complexes (dienyl = C5H5, C5H4Me, or C9H7; R = alkyl or benzyl; n= 1 or 2) with alkyl halides and other alkylating agents. The crystal structure of cis-[Fe2(?-C5H4Me)2(CO)3{C(NMe2)�}]I
18. Hydrido-complexes of molybdenum and tungsten with isonitrile and carbyne-type ligands