Time-Resolved Raman Detection of ν(Fe-O) in an Early Intermediate in the Reduction of O2 by Cytochrome Oxidase

Journal of the American Chemical Society

Volumn 111, Issue 16, 1989, Pages 6439-6440

  Varotsis, Constantinos ^a   Babcock, Gerald T ^a   Woodruff, William H ^b  

^a MICHIGAN STATE UNIVERSITY   (United States)

^b LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001158908     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00198a075     Document Type: Article

References (13)

1. 2 reaction in frozen samples by several groups. See: Chance, B.; Saronio, C.; Leigh, J. S. J. Biol. Chem. 1975, 250, 9226. Clore, G. M.; Andreasson, L. E.; Karlsson, B.; Aasa, R.; Malmstrom, B. G. Biochem. J. 1980, 185, 139. Chan, S. I.; Witt, S. N.; Blair, D. F. Chem. Scr. 1988, 28A, 51. For a review, see: Naqui, A.; Chance, B. Annu. Rev. Biochem. 1986, 55, 137.
2. Babcock, G. T.; Jean, J. M.; Johnston, L. N.; Palmer, G.; Woodruff, W. H. J. Am. Chem. Soc. 1984, 106, 8305. Babcock, G. T.; Jean, J. M.; Johnston, L. N.; Woodruff, W. H.; Palmer, G. J. Inorg. Biochem, 1985, 23, 243. Babcock, G. T. Biological Applications of Raman Scattering; Spiro, T. G., Ed.; Academic Press: New York, 1988; Vol. 3, p 295.
3. The details of the design and construction of the mixer and jet will be published elsewhere: Varotsis, C.; Babcock, G. T., in preparation. The 427-nm, 10-ns pulses were obtained by pumping stilbene with the third harmonic of a Quanta Ray DCR2A Nd:YAG laser.
4. Vanneste, W. H. Biochemistry 1966, 5, 838.
5. Varotsis, C.; Babcock, G. T., unpublished results.
6. Paeng, I. R.; Shiwaku, H.; Nakamoto, K. J. Am. Chem. Soc. 1988, 110, 1995.
7. Oertling, W. A.; Kean, R. T.; Wever, R.; Babcock, G. T. J. Am. Chem. Soc., submitted.
8. Blair, D. F.; Witt, S. N.; Chan, S. I. J. Am. Chem. Soc. 1985, 107, 7389.
9. Van Wart, H.; Zimmer, J. J. Biol. Chem. 1985, 250, 8372.
10. Wikstrom, M.; Krab, K.; Saraste, M. Cytochrome Oxidase, A Synthesis; Academic Press: New York, 1981.
11. Brunner, H. Naturwissenschaften 1974, 61, 129.
12. Nakamoto, K.; Paeng, I. R.; Kuroi, T.; Iosbe, T.; Oshio, H. J. Mol. Struct. 1988, 189, 293.
13. Wikström, M. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 4051.