Molecular association, chelate conformation and reactivity correlations in substituted o-phenylenebis(salicylidenaminato)copper(II) complexes: UV-visible, EPR and X-ray structural investigations

Polyhedron

Volumn 15, Issue 23, 1996, Pages 4133-4144

  Suresh, E ^a   Bhadbhade, M M ^a   Srinivas, D ^a  

^a CSIR CENTRAL SALT AND MARINE CHEMICALS RESEARCH INSTITUTE   (India)

Author keywords

Copper(II) complexes; EPR spectroscopy; Saloph; Structure; X ray

Indexed keywords

EID: 0001156484     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/0277-5387(96)00178-7     Document Type: Article

References (49)

1. J. W. Gohdes and W. H. Armstrong, Inorg. Chem. 1992, 31, 368; D. P. Kessissoglou, M. L. Krik, M. S. Lah, X. Li, C. Raptopoulou, W. E. Hatfield and V. L. Pecoraro, ibid 1992, 31, 5424.
2. J. W. Gohdes and W. H. Armstrong, Inorg. Chem. 1992, 31, 368; D. P. Kessissoglou, M. L. Krik, M. S. Lah, X. Li, C. Raptopoulou, W. E. Hatfield and V. L. Pecoraro, ibid 1992, 31, 5424.
3. P. E. Riley, V. L. Pecoraro, C. J. Corrano, J. A. Bonadies and K. N. Raymond, Inorg. Chem. 1986, 25, 154; M. Pesquali, F. Marchetti, C. Floriani and M. Cesari, ibid. 1980, 19, 1198.
4. P. E. Riley, V. L. Pecoraro, C. J. Corrano, J. A. Bonadies and K. N. Raymond, Inorg. Chem. 1986, 25, 154; M. Pesquali, F. Marchetti, C. Floriani and M. Cesari, ibid. 1980, 19, 1198.
5. B. J. Kennedy, A. C. McGrath, K. S. Murray, B. W. Skelton and A. H. White, Inorg. Chem. 1987, 26, 483.
6. C. T. Brewer, G. Brewer, L. May, J. Sitar and R. Wang, J. Chem. Soc., Dalton Trans. 1993, 151; W. Odenkirk, A. L. Rheingold and B. Boswich, J. Am. Chem. Soc. 1992, 114, 6392; G. P. Gupta, G. Lang, C. A. Kochi, B. Wang, W. R. Scheidt and C. A. Reed, Inorg. Chem. 1990, 29, 4234; A. Bencini, C. Bencilli, A. Caneschi, R. L. Carlin, A. Dei and D. Gatteschi, J. Am. Chem. Soc. 1985, 107, 8128; S. L. Kessel, R. M. Emberson, P. G. Debrunner and D. N. Hendrickson, Inorg. Chem. 1980, 19, 1170.
7. C. T. Brewer, G. Brewer, L. May, J. Sitar and R. Wang, J. Chem. Soc., Dalton Trans. 1993, 151; W. Odenkirk, A. L. Rheingold and B. Boswich, J. Am. Chem. Soc. 1992, 114, 6392; G. P. Gupta, G. Lang, C. A. Kochi, B. Wang, W. R. Scheidt and C. A. Reed, Inorg. Chem. 1990, 29, 4234; A. Bencini, C. Bencilli, A. Caneschi, R. L. Carlin, A. Dei and D. Gatteschi, J. Am. Chem. Soc. 1985, 107, 8128; S. L. Kessel, R. M. Emberson, P. G. Debrunner and D. N. Hendrickson, Inorg. Chem. 1980, 19, 1170.
8. C. T. Brewer, G. Brewer, L. May, J. Sitar and R. Wang, J. Chem. Soc., Dalton Trans. 1993, 151; W. Odenkirk, A. L. Rheingold and B. Boswich, J. Am. Chem. Soc. 1992, 114, 6392; G. P. Gupta, G. Lang, C. A. Kochi, B. Wang, W. R. Scheidt and C. A. Reed, Inorg. Chem. 1990, 29, 4234; A. Bencini, C. Bencilli, A. Caneschi, R. L. Carlin, A. Dei and D. Gatteschi, J. Am. Chem. Soc. 1985, 107, 8128; S. L. Kessel, R. M. Emberson, P. G. Debrunner and D. N. Hendrickson, Inorg. Chem. 1980, 19, 1170.
9. C. T. Brewer, G. Brewer, L. May, J. Sitar and R. Wang, J. Chem. Soc., Dalton Trans. 1993, 151; W. Odenkirk, A. L. Rheingold and B. Boswich, J. Am. Chem. Soc. 1992, 114, 6392; G. P. Gupta, G. Lang, C. A. Kochi, B. Wang, W. R. Scheidt and C. A. Reed, Inorg. Chem. 1990, 29, 4234; A. Bencini, C. Bencilli, A. Caneschi, R. L. Carlin, A. Dei and D. Gatteschi, J. Am. Chem. Soc. 1985, 107, 8128; S. L. Kessel, R. M. Emberson, P. G. Debrunner and D. N. Hendrickson, Inorg. Chem. 1980, 19, 1170.
10. C. T. Brewer, G. Brewer, L. May, J. Sitar and R. Wang, J. Chem. Soc., Dalton Trans. 1993, 151; W. Odenkirk, A. L. Rheingold and B. Boswich, J. Am. Chem. Soc. 1992, 114, 6392; G. P. Gupta, G. Lang, C. A. Kochi, B. Wang, W. R. Scheidt and C. A. Reed, Inorg. Chem. 1990, 29, 4234; A. Bencini, C. Bencilli, A. Caneschi, R. L. Carlin, A. Dei and D. Gatteschi, J. Am. Chem. Soc. 1985, 107, 8128; S. L. Kessel, R. M. Emberson, P. G. Debrunner and D. N. Hendrickson, Inorg. Chem. 1980, 19, 1170.
11. D. Chen and A. E. Martell, Inorg. Chem. 1987, 26, 1026; D. Chen, A. E. Martell and Y. Sun, Ibid. 1989, 28, 2647.
12. D. Chen and A. E. Martell, Inorg. Chem. 1987, 26, 1026; D. Chen, A. E. Martell and Y. Sun, Ibid. 1989, 28, 2647.
13. R. D. Jones, D. A. Summerville and F. Basolo, Chem. Rev. 1979, 79, 139.
14. K. Srinivasan, P. Michaud and J. K. Kochi, J. Am. Chem. Soc. 1986, 108, 2308; P. S. Dixit and K. Srinivasan, Inorg. Chem. 1988, 27, 4507.
15. K. Srinivasan, P. Michaud and J. K. Kochi, J. Am. Chem. Soc. 1986, 108, 2308; P. S. Dixit and K. Srinivasan, Inorg. Chem. 1988, 27, 4507.
16. C. P. Horwitz, S. E. Creager and R. W. Murray, Inorg. Chem. 1990, 29, 1006; W. Zhang, L. Loebach, S. R. Wilson and E. N. Jacobsen, J. Am. Chem. Soc. 1990, 112, 2801; Z. Li, K. R. Consar and E. N. Jacobsen, ibid. 1993, 115, 5326; E. N. Jacobsen, W. Zhang, A. R. Muci, J. R. Ecker and L. Deng, ibid. 1991, 113, 7063.
17. C. P. Horwitz, S. E. Creager and R. W. Murray, Inorg. Chem. 1990, 29, 1006; W. Zhang, L. Loebach, S. R. Wilson and E. N. Jacobsen, J. Am. Chem. Soc. 1990, 112, 2801; Z. Li, K. R. Consar and E. N. Jacobsen, ibid. 1993, 115, 5326; E. N. Jacobsen, W. Zhang, A. R. Muci, J. R. Ecker and L. Deng, ibid. 1991, 113, 7063.
18. C. P. Horwitz, S. E. Creager and R. W. Murray, Inorg. Chem. 1990, 29, 1006; W. Zhang, L. Loebach, S. R. Wilson and E. N. Jacobsen, J. Am. Chem. Soc. 1990, 112, 2801; Z. Li, K. R. Consar and E. N. Jacobsen, ibid. 1993, 115, 5326; E. N. Jacobsen, W. Zhang, A. R. Muci, J. R. Ecker and L. Deng, ibid. 1991, 113, 7063.
19. C. P. Horwitz, S. E. Creager and R. W. Murray, Inorg. Chem. 1990, 29, 1006; W. Zhang, L. Loebach, S. R. Wilson and E. N. Jacobsen, J. Am. Chem. Soc. 1990, 112, 2801; Z. Li, K. R. Consar and E. N. Jacobsen, ibid. 1993, 115, 5326; E. N. Jacobsen, W. Zhang, A. R. Muci, J. R. Ecker and L. Deng, ibid. 1991, 113, 7063.
20. W. M. Coleman, R. K. Boggess, J. W. Hughes and L. T. Taylor, Inorg. Chem. 1981, 20, 700.
21. M. M. Bhadbhade and D. Srinivas, Inorg. Chem. 1993, 32, 5458.
22. W. R. Scheidt and C. A. Reed, Chem. Rev. 1981, 81, 543.
23. M. M. Taqui Khan, S. A. Mirza, Z. A. Shaikh, Ch. Sreelatha, P. Paul, R. S. Shukla, D. Srinivas, A. Prakash Rao, S. H. R. Abdi, S. D. Bhatt and G. Ramachandraiah, Polyhedron 1992, 11, 1821; M. M. Taqui Khan, Ch. Sreelatha, S. A. Mirza, G. Ramachandraiah and S. H. R. Abdi, Inorg. Chim. Acta 1988, 154, 103.
24. M. M. Taqui Khan, S. A. Mirza, Z. A. Shaikh, Ch. Sreelatha, P. Paul, R. S. Shukla, D. Srinivas, A. Prakash Rao, S. H. R. Abdi, S. D. Bhatt and G. Ramachandraiah, Polyhedron 1992, 11, 1821; M. M. Taqui Khan, Ch. Sreelatha, S. A. Mirza, G. Ramachandraiah and S. H. R. Abdi, Inorg. Chim. Acta 1988, 154, 103.
25. H. Montgomery and B. Morosin, Acta Cryst. 1961, 14, 551.
26. G. D. Fallon and B. M. Gatehouse, Acta Cryst. 1976, B32, 2591.
27. A. Radha, M. Seshasayee, K. Ramalingam and G. Aravamudan, Acta Cryst. 1985, C41, 1169.
28. N. B. Pahor, P. M. Calligaris, P. Delise, G. Dodic, G. Nardin and L. Randaccio, J. Chem. Soc., Dalton Trans. 1976, 2478.
29. D. D. Perrin, W. L. F. Armarego and D. R. Perrin, Purification of Laboratory Chemicals, Pergamon Press, Oxford (1980).
30. P. Main, G. Germain, J. P. Declercq and M. M. Wolfson, MULTAN 82: A System of Computer Programs for the Automatic Solution of Crystal Structures from X-ray Data University of York, York (1982).
31. A. C. T. North, D. C. Phillips and F. S. Mathews, Acta Cryst. 1968, A24, 351.
32. B. A. Frenz & Associates, SDP Structure Determination Package, College Station, TX, USA and Enraf-Nonius, Delft, The Netherlands (1985).
33. C. K. Johnson, ORTEP, Report ORNL-3194, Oak Ridge National Laboratory, Oak Ridge, TN, USA (1976).
34. C. Cassoux and A. Gleizes, Inorg. Chem. 1980, 19, 665.
35. L. G. Marzilli, M. F. Summers, N. Bresciani, E. Pahor, J.-P. Charland and L. Randaccio, J. Am. Chem. Soc. 1985, 107, 6680.
36. R. Delasi, S. L. Holt and B. Post, Inorg. Chem. 1971, 10, 1498.
37. M. Gerloch and F. E. Mabbs, J. Chem. Soc. (A) 1967, 1900.
38. N. Brescianl, M. Calligaris, G. Nardin and L. Randaccio, J. Chem. Soc., Dalton Trans. 1974, 1606.
39. W. B. Lewis and L. O. Morgan, Trans. Met. Chem. 1968, 4, 33.
40. A. H. Maki and B. R. McGarvey, J. Chem. Phys. 1958, 29, 31, 35; B. R. McGarvey, J. Phys. Chem. 1956, 60, 71.
41. A. H. Maki and B. R. McGarvey, J. Chem. Phys. 1958, 29, 31, 35; B. R. McGarvey, J. Phys. Chem. 1956, 60, 71.
42. Gutmann Donor Number (DN) was chosen as a measure of the Lewis basicity of the solvent molecules. V. Gutmann, The Donor-Acceptor Approach to Molecular Interactions, Plenum Press, New York (1978); V. Gutmann, Coordination Chemistry in Non-aqueous Solutions, Springer, Vienna (1968).
43. Gutmann Donor Number (DN) was chosen as a measure of the Lewis basicity of the solvent molecules. V. Gutmann, The Donor-Acceptor Approach to Molecular Interactions, Plenum Press, New York (1978); V. Gutmann, Coordination Chemistry in Non-aqueous Solutions, Springer, Vienna (1968).
44. T. N. Waters and D. J. Hall, J. Chem. Soc. 1959, 1200.
45. D. Kivelson and R. Neiman, J. Chem. Phys. 1961, 35, 149.
46. B. J. Kennedy, G. D. Fallon, B. M. K. C. Gatehouse and K. S. Murray, Inorg. Chem. 1984, 23, 580.
47. F. M. Ashmawy, A. R. Ujaimi, C. A. McAuliffe, R. V. Parish and R. G. Richard, Inorg. Chim. Acta 1991, 187, 155.
48. P. Coggon, A. T. McPhail, F. E. Mabbs and V. N. McIachlan, J. Chem. Soc. (A) 1971, 1014.
49. N. Bresciani, M. Calligaris, G. Nardin and L. Randaccio, J. Chem. Soc., Dalton Trans. 1974, 498.