Reactivity and Mechanism in Oxidative Addition to Palladium(II) and Reductive Elimination from Palladium(IV) and an Estimate of the Palladium-Methyl Bond Energy

Organometallics

Volumn 7, Issue 6, 1988, Pages 1363-1367

  Byers, Peter K ^a   Canty, Allan J ^a   Crespo, Margarita ^b   Puddephatt, Richard J ^b   Scott, John D ^c  

^a UNIVERSITY OF TASMANIA   (Australia)

^b UNIVERSITY OF WESTERN ONTARIO   (Canada)

^c 3M Canada Company   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001147716     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om00096a021     Document Type: Article

References (18)

1. For a recent review, see: Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987.
2. Ozawa, F.; Fujimori, M.; Yamamoto, T.; Yamamoto, A. Organometallics 1986, 5, 2144 and references therein.
3. Milstein, D.; Stille, J. K. J. Am. Chem. Soc. 1979, 101, 4981.
4. Loar, M. K.; Stille, J. K. J. Am. Chem. Soc. 1981, 103, 4174.
5. Moravsky, A.; Stille, J. K. J. Am. Chem. Soc. 1981, 103, 4182.
6. Kurosawa, H.; Emoto, M.; Urabe, A. J. Chem. Soc., Chem. Commun. 1984, 968.
7. Byers, P. K.; Canty, A. J.; Skelton, B. W.; White, A. H. J. Chem. Soc., Chem. Commun. 1986, 1722.
8. Byers, P. K.; Canty, A. J.; Skelton, B. W.; White, A. H. J. Chem. Soc., Chem. Commun. 1987, 1093.
9. Byers, P. K.; Canty, A. J.; Skelton, B. W.; White, A. H. J. Organomet. Chem. 1987, 336, C55.
10. Crespo, M.; Puddephatt, R. J. Organometallics 1987, 6, 2548. Scott, J. D.; Puddephatt, R. J. Organometallics 1985, 4, 1221.
11. Monaghan, P. K.; Puddephatt, R. J. J. Chem. Soc., Dalton Trans., in press.
12. Chock, P. B.; Halpern, J. J. Am. Chem. Soc. 1966, 88, 3511.
13. Jawad, J. K.; Puddephatt, R. J. J. Chem. Soc., Dalton Trans. 1977, 1466.
14. Brown, M. P.; Puddephatt, R. J.; Upton, C. E. E. J. Chem. Soc., Dalton Trans. 1974, 2457.
15. It is important to note that, although the thermochemical data for the solid state are precise, the correction to the gas phase depends on assumptions that cannot be verified. Hence the error limits to E(PdC) are minimum values. Mortimer, C. T.; McNaughton, J. L.; Puddephatt, R. J. J. Chem. Soc., Dalton Trans. 1972, 1265 and references therein.
16. 2], the M-C bond is slightly shorter and the M-P bond slightly longer when = Pd compared to when M= Pt. Again this supports a strong Pd-C bond. Wisner, J. M.; Bartczak, T. J.; Ibers, J. A. Organometallics 1985, 5, 2044.
17. Brookhart, M.; Green, M. L. H. J. Organomet. Chem. 1983, 250, 395.
18. Periana, R. A.; Bergman, R. G. J. Am. Chem. Soc. 1984, 106, 7272. For activation of ethane at a Pt surface, see: Parshall, G. W. Homogeneous Catalysis; Wiley: New York, 1980; p 181.