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Volumn 100, Issue 2, 1994, Pages 1761-1764

The existence of structure progressions and wetting transitions in intermediately disordered monolayer alkyl chain assemblies

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Indexed keywords


EID: 0001143320     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.466604     Document Type: Article
Times cited : (63)

References (43)
  • 25
    • 13244274186 scopus 로고
    • Thicknesses were determined using a single wavelength (623.8 nm) null-ellipsometer as previously described The FRS measurements of total proton surface density were carried out at the ion accelerator facility at Cornell University. The use of deuterated alcohols showed adsorbed [formula ommitted] was not an interfering factor. The normal incidence TIRS measurements were done at [formula ommitted] resolution on a Bomem MB 100 series Fourier transform spectrometer. Fringing effects were minimized both by use of wedged Si( 100) wafers (Harrick Scientific). Sessile drop contact angle measurements were conducted in a saturated vapor of the probe liquid at [formula ommitted] and are reported as multiple sample averages with five spots analyzed per sample
    • (1987) Langmuir , vol.1 , pp. 52
    • Allara, D.L.1    Nuzzo, R.G.2
  • 33
    • 4043166092 scopus 로고
    • Connections between the chain-length induced structural transitions and 2D systems can be made by invoking recent studies of ordering in 2D vortex lattices on superconductors in which magnetic fields have been observed to induce ordering transitions from isotropic phases to hexatic phases by unpinning pair vortices from a disordered defect lattice. One can make an approximate conceptual analogy between the magnetic field as an unpinning force in the vortex field and intermolecular interactions between alkyl chains, which, in the limit of sufficiently flexible and long molecules, should tend to overide the pinning lattice disorder in regions towards the termini of the chains (away from the substrate) and thereby force the molecular system into a different structural phase, relatively uncorrelated with the pinning lattice
    • (1990) Phys. Rev. Lett. , vol.64 , pp. 2312
    • Murray, C.A.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.