Nickel Complexes as Antioxidants. Inhibition of Aldehyde Autoxidation by Nickel(II) Tetraazamacrocycles

Inorganic Chemistry

Volumn 35, Issue 23, 1996, Pages 6632-6633

  Nam, Wonwoo ^a   Baek, Seung Joong ^a   Lee, Kyoung Ah ^a   Ahn, Byung Tae ^a   Muller, James G ^b   Burrows, Cynthia J ^b   Valentine, Joan Selverstone ^c  

^a Ewha Womans University   (South Korea)

^b UNIVERSITY OF UTAH   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001138169     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9513651     Document Type: Article

References (13)

1. (a) Nam, W.; Kim, H. J.; Kim, S. H.; Ho, R. Y. N.; Valentine, J. S. Inorg. Chem. 1996, 35, 1045-1049.
2. (b) An analysis of much of the recent literature on this subject can be found in: Finke, R. G. J. Mol. Catal., in press.
3. (a) Simandi, L. I., Ed. Catalytic Activation of Dioxygen by Metal Complexes; Kluwer Academic Publishers: Dordrecht, 1992; pp 318-331.
4. (b) Sheldon, R. A., Kochi, J. K., Eds. Metal-Catalyzed Oxidations of Organic Compounds; Academic Press: New York, 1981; pp 359-363.
5. (c) Nagata, T.; Imagawa, K.; Yamada, T.; Mukaiyama, T. Chem. Lett. 1994, 1259-1262 and references therein.
6. II reduction potentials for the nickel complexes were obtained from the following papers: (a) Lovecchio, F. V.; Gore, E. S.; Busch, D. H. J. Am. Chem. Soc. 1974, 96, 3109-3118. (b) Muller, J. G.; Chen, X.; Dadiz, A. C.; Rokita, S. E.; Burrows, C. J. J. Am. Chem. Soc. 1992, 114, 6407-6411. (c) Fabbrizzi, L.; Poggi, A. Inorg. Chim. Acta 1980, 39, 207-210.
7. II reduction potentials for the nickel complexes were obtained from the following papers: (a) Lovecchio, F. V.; Gore, E. S.; Busch, D. H. J. Am. Chem. Soc. 1974, 96, 3109-3118. (b) Muller, J. G.; Chen, X.; Dadiz, A. C.; Rokita, S. E.; Burrows, C. J. J. Am. Chem. Soc. 1992, 114, 6407-6411. (c) Fabbrizzi, L.; Poggi, A. Inorg. Chim. Acta 1980, 39, 207-210.
8. II reduction potentials for the nickel complexes were obtained from the following papers: (a) Lovecchio, F. V.; Gore, E. S.; Busch, D. H. J. Am. Chem. Soc. 1974, 96, 3109-3118. (b) Muller, J. G.; Chen, X.; Dadiz, A. C.; Rokita, S. E.; Burrows, C. J. J. Am. Chem. Soc. 1992, 114, 6407-6411. (c) Fabbrizzi, L.; Poggi, A. Inorg. Chim. Acta 1980, 39, 207-210.
9. Zeigerson, E.; Ginzburg, G.; Schwartz, N.; Luz, Z.; Meyerstein, D. J. Chem. Soc., Chem. Commun. 1979, 241-243.
10. The yield of cyclohexene oxide after 8 h of reaction was 1.6 mmol with cobalt(III) acetylacetonate alone and 1.5 mmol with cobalt(III) acetylacetonate plus nickel(III) cyclam.
11. (a) Boga, E; Peintler, G.; Nagypal, I. J. Am. Chem. Soc. 1990, 112, 151-153.
12. (b) Roelofs, M. G.; Wasserman, E.; Jensen, J. H. J. Am. Chem. Soc. 1987, 109, 4207-4217.
13. 3CN (5 mL). The oxidation of aldehyde was initiated within 3 h, whereas the oxidation reaction was not initiated for 8 h when cyclohexene (3 mmol) was added to the same reaction solution.