Synthesis, Crystal Structure, and Magnetic Behavior of (μ3-CO3)[Cu3(Medpt)3(ClO 4)3]ClO4: A New Copper(II) Carbonato-Bridged Complex with a Triangular Array

Inorganic Chemistry

Volumn 35, Issue 1, 1996, Pages 248-251

  Escuer, Albert ^a   Vicente, Ramon ^a   Peñalba, Evaristo ^a   Solans, Xavier ^a   Font Bardía, Mercé ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001135424     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic950331q     Document Type: Article

References (25)

1. Comprehensive Coordination Chemistry; Pergamon Press: Oxford, 1987; Vol. 2.
2. Some recent dimers for M = Cu may be in the following, (a) Sletten, J.; Hope, H.; Julve, M.; Kahn, O.; Verdaguer, M.; Dworkin, A. Inorg. Chem. 1988, 27, 542. (b) Tyeclar, Z.; Partha, P. P.; Jacobson, R.; Farooq, A.; Karlin, K. D.; Zubieta, J. J. Am. Chem. Soc. 1989, 111, 388. (c) Kitajima, N.; Koda, T.; Hashimoto, S.; Kitagawa, T.; Morooka, Y. J. Am. Chem. Soc. 1991, 113, 5664. (d) Kitajima, N.; Hikichi, S.; Tanaka, M.; Moro-oka, Y. J. Am. Chem. Soc. 1993, 115, 5496. (e) BrenK, A. L.; Byriel, K. A.; Fairlie, D. P.; Gahan, L R.; Hanson, G. R.; Hawkins, C. J.; Jones, A.; Kennard, C. H. L.; Moubaraki, B.; Murray, K. S. Inorg. Chem. 1994, 33, 3549. Reference 2e also includes carbonate dimers with Ni, Co, and Fe.
3. Some recent dimers for M = Cu may be in the following, (a) Sletten, J.; Hope, H.; Julve, M.; Kahn, O.; Verdaguer, M.; Dworkin, A. Inorg. Chem. 1988, 27, 542. (b) Tyeclar, Z.; Partha, P. P.; Jacobson, R.; Farooq, A.; Karlin, K. D.; Zubieta, J. J. Am. Chem. Soc. 1989, 111, 388. (c) Kitajima, N.; Koda, T.; Hashimoto, S.; Kitagawa, T.; Morooka, Y. J. Am. Chem. Soc. 1991, 113, 5664. (d) Kitajima, N.; Hikichi, S.; Tanaka, M.; Moro-oka, Y. J. Am. Chem. Soc. 1993, 115, 5496. (e) BrenK, A. L.; Byriel, K. A.; Fairlie, D. P.; Gahan, L R.; Hanson, G. R.; Hawkins, C. J.; Jones, A.; Kennard, C. H. L.; Moubaraki, B.; Murray, K. S. Inorg. Chem. 1994, 33, 3549. Reference 2e also includes carbonate dimers with Ni, Co, and Fe.
4. Some recent dimers for M = Cu may be in the following, (a) Sletten, J.; Hope, H.; Julve, M.; Kahn, O.; Verdaguer, M.; Dworkin, A. Inorg. Chem. 1988, 27, 542. (b) Tyeclar, Z.; Partha, P. P.; Jacobson, R.; Farooq, A.; Karlin, K. D.; Zubieta, J. J. Am. Chem. Soc. 1989, 111, 388. (c) Kitajima, N.; Koda, T.; Hashimoto, S.; Kitagawa, T.; Morooka, Y. J. Am. Chem. Soc. 1991, 113, 5664. (d) Kitajima, N.; Hikichi, S.; Tanaka, M.; Moro-oka, Y. J. Am. Chem. Soc. 1993, 115, 5496. (e) BrenK, A. L.; Byriel, K. A.; Fairlie, D. P.; Gahan, L R.; Hanson, G. R.; Hawkins, C. J.; Jones, A.; Kennard, C. H. L.; Moubaraki, B.; Murray, K. S. Inorg. Chem. 1994, 33, 3549. Reference 2e also includes carbonate dimers with Ni, Co, and Fe.
5. Some recent dimers for M = Cu may be in the following, (a) Sletten, J.; Hope, H.; Julve, M.; Kahn, O.; Verdaguer, M.; Dworkin, A. Inorg. Chem. 1988, 27, 542. (b) Tyeclar, Z.; Partha, P. P.; Jacobson, R.; Farooq, A.; Karlin, K. D.; Zubieta, J. J. Am. Chem. Soc. 1989, 111, 388. (c) Kitajima, N.; Koda, T.; Hashimoto, S.; Kitagawa, T.; Morooka, Y. J. Am. Chem. Soc. 1991, 113, 5664. (d) Kitajima, N.; Hikichi, S.; Tanaka, M.; Moro-oka, Y. J. Am. Chem. Soc. 1993, 115, 5496. (e) BrenK, A. L.; Byriel, K. A.; Fairlie, D. P.; Gahan, L R.; Hanson, G. R.; Hawkins, C. J.; Jones, A.; Kennard, C. H. L.; Moubaraki, B.; Murray, K. S. Inorg. Chem. 1994, 33, 3549. Reference 2e also includes carbonate dimers with Ni, Co, and Fe.
6. Some recent dimers for M = Cu may be in the following, (a) Sletten, J.; Hope, H.; Julve, M.; Kahn, O.; Verdaguer, M.; Dworkin, A. Inorg. Chem. 1988, 27, 542. (b) Tyeclar, Z.; Partha, P. P.; Jacobson, R.; Farooq, A.; Karlin, K. D.; Zubieta, J. J. Am. Chem. Soc. 1989, 111, 388. (c) Kitajima, N.; Koda, T.; Hashimoto, S.; Kitagawa, T.; Morooka, Y. J. Am. Chem. Soc. 1991, 113, 5664. (d) Kitajima, N.; Hikichi, S.; Tanaka, M.; Moro-oka, Y. J. Am. Chem. Soc. 1993, 115, 5496. (e) BrenK, A. L.; Byriel, K. A.; Fairlie, D. P.; Gahan, L R.; Hanson, G. R.; Hawkins, C. J.; Jones, A.; Kennard, C. H. L.; Moubaraki, B.; Murray, K. S. Inorg. Chem. 1994, 33, 3549. Reference 2e also includes carbonate dimers with Ni, Co, and Fe.
7. Recent reference for Ni: Kempe, R.; Sieler, J.; Walther, D.; Reinhold, J.; Rommel, K. Z. Anorg. Allg. Chem. 1993, 619, 1105. For Co: Harada, H.; Kodera, M; VucKovic, G.; Matsumoto, N.; Kida, S. Inorg. Chem. 1991, 30, 1190. For Fe: Arulsamy, N.: Goodson, P. A.; Hodgson, D. J.; Glerup, G.; Michelsen, K. Inorg. Chim. Acta 1994, 216, 2L For Cr: Spiccia, L.; Fallon, G. D.; Markiewicz, A.; Murray, K S.; Riesen, H. Inorg. Chem. 1992, 31, 1066.
8. Recent reference for Ni: Kempe, R.; Sieler, J.; Walther, D.; Reinhold, J.; Rommel, K. Z. Anorg. Allg. Chem. 1993, 619, 1105. For Co: Harada, H.; Kodera, M; VucKovic, G.; Matsumoto, N.; Kida, S. Inorg. Chem. 1991, 30, 1190. For Fe: Arulsamy, N.: Goodson, P. A.; Hodgson, D. J.; Glerup, G.; Michelsen, K. Inorg. Chim. Acta 1994, 216, 2L For Cr: Spiccia, L.; Fallon, G. D.; Markiewicz, A.; Murray, K S.; Riesen, H. Inorg. Chem. 1992, 31, 1066.
9. Recent reference for Ni: Kempe, R.; Sieler, J.; Walther, D.; Reinhold, J.; Rommel, K. Z. Anorg. Allg. Chem. 1993, 619, 1105. For Co: Harada, H.; Kodera, M; VucKovic, G.; Matsumoto, N.; Kida, S. Inorg. Chem. 1991, 30, 1190. For Fe: Arulsamy, N.: Goodson, P. A.; Hodgson, D. J.; Glerup, G.; Michelsen, K. Inorg. Chim. Acta 1994, 216, 2L For Cr: Spiccia, L.; Fallon, G. D.; Markiewicz, A.; Murray, K S.; Riesen, H. Inorg. Chem. 1992, 31, 1066.
10. Recent reference for Ni: Kempe, R.; Sieler, J.; Walther, D.; Reinhold, J.; Rommel, K. Z. Anorg. Allg. Chem. 1993, 619, 1105. For Co: Harada, H.; Kodera, M; VucKovic, G.; Matsumoto, N.; Kida, S. Inorg. Chem. 1991, 30, 1190. For Fe: Arulsamy, N.: Goodson, P. A.; Hodgson, D. J.; Glerup, G.; Michelsen, K. Inorg. Chim. Acta 1994, 216, 2L For Cr: Spiccia, L.; Fallon, G. D.; Markiewicz, A.; Murray, K S.; Riesen, H. Inorg. Chem. 1992, 31, 1066.
11. Kolks, G.; Lippard, S. J.; WaszczaK, J. V. J. Am. Chem. Soc. 1980, 702, 4832.
12. Einstein, F. W. B.; Willis, A. C. Inorg. Chem. 1981, 20, 609. Alvarez, R.; Atwood, J. L.; Carmona, E.; Perez, P. J.; Poveda, M. L.; Rogers, R. D. Inorg. Chem. 1991, 30, 1493.
13. Einstein, F. W. B.; Willis, A. C. Inorg. Chem. 1981, 20, 609. Alvarez, R.; Atwood, J. L.; Carmona, E.; Perez, P. J.; Poveda, M. L.; Rogers, R. D. Inorg. Chem. 1991, 30, 1493.
14. Slerten, J. Acta Chem Scand., Ser. A 1984, 38, 491. Jeter, D Y.; Hodgson, D. J.; Hatfield, W. E. Inorg. Chem. 1972, 11, 185.
15. Slerten, J. Acta Chem Scand., Ser. A 1984, 38, 491. Jeter, D Y.; Hodgson, D. J.; Hatfield, W. E. Inorg. Chem. 1972, 11, 185.
16. Healy, P C.; White, A. H. J. Chem. Soc. 1972, 1913. Brotherton, P. D., White, A. H. J. Chem. Soc: 1973. 2338. Gregson, A. K., Healy, P. C. Inorg. Chem. 1978, 17, 2969.
17. Healy, P C.; White, A. H. J. Chem. Soc. 1972, 1913. Brotherton, P. D., White, A. H. J. Chem. Soc: 1973. 2338. Gregson, A. K., Healy, P. C. Inorg. Chem. 1978, 17, 2969.
18. Healy, P C.; White, A. H. J. Chem. Soc. 1972, 1913. Brotherton, P. D., White, A. H. J. Chem. Soc: 1973. 2338. Gregson, A. K., Healy, P. C. Inorg. Chem. 1978, 17, 2969.
19. Curtis, N. F.; Hay, R. W.; Curtis, Y. M. J. Chem. Soc. 1968, 182.
20. Chaudhuri, P.; Karpenstein, I.; Winter, M.; Butzlaff, C.; Bill, E.; Trautwein, A. X.; Flörke, U.; Haupt, H. J. J. Chem. Soc., Chem. Commun. 1992, 321, and references therein.
21. Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467.
22. Sheldrick, G. M. Manuscript in preparation.
23. International Tables for X-Ray Crystallography, Kynoch Press: Birmingham, England, 1974; Vol. IV. pp 99-110 and 149.
24. Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993.
25. Mealli, C.; Proserpio, D. M. J. Chem. Educ. 1990, 67, 3399.