Copper-catalyzed direct amination of nitrobenzenes with O-alkylhydroxylamines

Journal of Organic Chemistry

Volumn 61, Issue 2, 1996, Pages 442-443

  Seko, Shinzo ^a   Kawamura, Norio ^a  

^a SUMITOMO CHEMICAL CO LTD   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001124331     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo951903r     Document Type: Article

References (26)

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17. For direct animations of 1,3-dinitroarenes or bicyclic nitroarenes with hydroxylamine, see: (a) Möler, F. In Houben-Weil Methoden der Organische Chemie; Muller, E., Ed.; G. Thieme: Stuttgart, 1957; Vol. 11/1, pp 17-19. (b) Baumgarten, H. E. J. Am. Chem. Soc. 1955, 77, 5109-5112. (c) Nasielski-Hinkens, R.; Kotel, J.; Lecloux, T.; Nasielski, J. Synth. Commun. 1989, 19, 511-514.
18. For direct animations of 1,3-dinitroarenes or bicyclic nitroarenes with hydroxylamine, see: (a) Möler, F. In Houben-Weil Methoden der Organische Chemie; Muller, E., Ed.; G. Thieme: Stuttgart, 1957; Vol. 11/1, pp 17-19. (b) Baumgarten, H. E. J. Am. Chem. Soc. 1955, 77, 5109-5112. (c) Nasielski-Hinkens, R.; Kotel, J.; Lecloux, T.; Nasielski, J. Synth. Commun. 1989, 19, 511-514.
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20. 2 and purified by silica gel thin layer chromatography.
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23. New compound (see supporting information).
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25. 2OMe, t-BuOK, and CuCl exhibited two singlets for the methoxy groups of two different species at δ 3.35 and δ 3.22, although in the absence of CuCl it indicated only one singlet for the methoxy group at δ 3.34.
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