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Edge fits were done using EXAFSPAK, which treats the main absorption peak and other resonances as pseudo-Voigt peaks (mixture of Lorenztian and Gaussian shapes) and the discontinuous edge step function as the integral of a pseudo-Voigt function. The Ac(III, IV) spectra were fit using one peak plus the step function, while the actinyl XANES fits included a second peak to fit the MS resonance.
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The solution temperatures are estimated to be 25 ± 1°C on the basis of readings taken periodically in the vicinity of the experimental hutch
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The solution temperatures are estimated to be 25 ± 1°C on the basis of readings taken periodically in the vicinity of the experimental hutch.
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