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22244481818
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We omit the angular momentum dependence from Eq. (8) after Ref. 13. This is a reasonable approximation because the clusters generated in a supersonic expansion have low angular momenta, and the rotational constants of the reactant and the transition state must be similar to each other.
-
We omit the angular momentum dependence from Eq. (8) after Ref. 13. This is a reasonable approximation because the clusters generated in a supersonic expansion have low angular momenta, and the rotational constants of the reactant and the transition state must be similar to each other.
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43
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44
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22244488687
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The numbers of states and the densities of states are calculated with a direct counting algorithm for harmonic oscillators
-
The numbers of states and the densities of states are calculated with a direct counting algorithm for harmonic oscillators.
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45
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22244470683
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private communications
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H. J. Neusser (private communications).
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Neusser, H.J.1
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47
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22244475731
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p is the width of the parent ion signal
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p is the width of the parent ion signal;
-
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49
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22244483717
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′ at this photon energy
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′ at this photon energy.
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50
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3743100204
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in edited by M. T. Bowers Academic, New York
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J. L. Franklin, in Gas Phase Ion Chemistry, edited by M. T. Bowers (Academic, New York, 1979), Vol. 1, p. 273.
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Franklin, J.L.1
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0002317324
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in edited by H. Haberland Springer, Berlin
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M. F. Jarrold, in Clusters of Atoms and Molecules, edited by H. Haberland (Springer, Berlin, 1994), p. 163.
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Jarrold, M.F.1
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58
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22244436876
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ex≥18ns. In the simulation, Δt is taken to be 1 ns
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ex≥18ns. In the simulation, Δt is taken to be 1 ns.
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59
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22244437204
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+ is calculated by using Eq. (4) with t=11.13μs. Then the population distribution of the transient dimer is calculated by using Eq. (22)
-
+ is calculated by using Eq. (4) with t=11.13μs. Then the population distribution of the transient dimer is calculated by using Eq. (22).
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