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Volumn 90, Issue 10, 1989, Pages 5612-5621

The external heavy atom effect: Theory of spin-orbit coupling of alkali and noble metals in rare gas matrices

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0001109150     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.456414     Document Type: Article
Times cited : (38)

References (52)
  • 36
    • 84953359428 scopus 로고    scopus 로고
    • k is defined as [formula omitted] that is, the ratio of the metal SO splitting constant in the matrix vs in the gas phase.
  • 49
    • 84953355687 scopus 로고    scopus 로고
    • The secular equation is: [formula omitted] where [formula omitted] The expression under the square root, upon solution of the resulting quadratic equation, becomes [formula omitted] after substitution of the Wolfberg-Helmholtz approximation in Eq. (15).
  • 51
    • 85034902063 scopus 로고    scopus 로고
    • In Ref. 28, Schatz and co-workers refer to unpublished work on K in Ar, Kr and Xe and state that the k is negative in K/Kr and K/Xe but is positive in K/Ar.
  • 52
    • 84953347491 scopus 로고    scopus 로고
    • The metal atom is at the origin of the right-hand side Cartesian coordinate system. The rare gas atoms lie on the axes and are numbered as follows: [formula omitted] [formula omitted] [formula omitted] [formula omitted] [formula omitted]


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.