Proton-transfer processes in well-defined media: Experimental investigation of photoinduced and thermal proton-transfer processes in single crystals of 2-(2,4-dinitrobenzyl)pyridine derivatives

Journal of Physical Chemistry

Volumn 100, Issue 40, 1996, Pages 16175-16186

  Scherl, Michael ^a   Haarer, Dietrich ^a   Fischer, Jean ^b   DeCian, André ^b   Lehn, Jean Marie ^c   Eichen, Yoav ^c,d  

^a UNIVERSITY OF BAYREUTH   (Germany)

^b UNIVERSITÉ LOUIS PASTEUR   (France)

^c Laboratoire de Cristallochimie et de Chimie Structurale   (France)

^d TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001104371     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9609242     Document Type: Article

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57. (a) Center-to-center distances.
58. (b) Using a repetitive grinding irradiating cycle until the powders did not change color in grinding.
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60. (d) The relative quantum yield is given by the formation of the phototautomer, assuming that the absolute quantum yield is low (<0.2, in our experiments, no saturation effect could be observed in the high-temperature regime) and other nonradiative deactivation processes are not temperature dependent.
61. 25 and assuming similar extinction coefficients for the different "NH" tautomers.
62. (f) Our measured barriers and lifetimes are somewhat different from those reported in ref 15a.
63. (g) Calculation were performed using a data set where the coordinate of all atoms but the pyridine nitrogen, the benzylic protons, and the o-nitro group are fixed.
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