A New Class of Luminescent Polypyridine Complexes of Rhenium(I) Containing cis-Carbonyl Ligands

Inorganic Chemistry

Volumn 37, Issue 11, 1998, Pages 2618-2619

  Schutte, Erick ^a   Helms, Jeffrey B ^a   Woessner, Stephen M ^a   Bowen, John ^a   Patrick Sullivan, B ^a  

^a UNIVERSITY OF WYOMING   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001097390     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971199s     Document Type: Article

References (38)

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9. Some leading references: (a) Wallace, L.; Rillema, D. P. Inorg. Chem. 1993, 32, 3836. (b) Worl, L. A.; Duesing, R.; Chen, P.; Delia Ciana, L.; Meyer, T. J. J. Chem. Soc., Dalton Trans. 1991, 843. Sacksteder, L.; Zipp, A. P.; Brown, E. A.; Streich, J.; Demas, J. N.; Degraff, B. A. Inorg. Chem. 1990, 29, 4335. Hino, J. K.; Della Ciana, L.; Dressick, W. J.; Sullivan, B. P. Inorg. Chem. 1992, 31, 1072. (e) Paulson, S.; Morris, K.; Sullivan, B. P. J. Chem. Soc., Chem. Commun. 1992, 1615. (f) Shaver, R. J.; Rillema, D. P. Inorg. Chem. 1992, 31, 4101. (g) Striplin, D. R.; Crosby, G. A. Chem. Phys. Lett. 1994, 227, 426.
10. Some leading references: (a) Wallace, L.; Rillema, D. P. Inorg. Chem. 1993, 32, 3836. (b) Worl, L. A.; Duesing, R.; Chen, P.; Delia Ciana, L.; Meyer, T. J. J. Chem. Soc., Dalton Trans. 1991, 843. Sacksteder, L.; Zipp, A. P.; Brown, E. A.; Streich, J.; Demas, J. N.; Degraff, B. A. Inorg. Chem. 1990, 29, 4335. Hino, J. K.; Della Ciana, L.; Dressick, W. J.; Sullivan, B. P. Inorg. Chem. 1992, 31, 1072. (e) Paulson, S.; Morris, K.; Sullivan, B. P. J. Chem. Soc., Chem. Commun. 1992, 1615. (f) Shaver, R. J.; Rillema, D. P. Inorg. Chem. 1992, 31, 4101. (g) Striplin, D. R.; Crosby, G. A. Chem. Phys. Lett. 1994, 227, 426.
11. Some leading references: (a) Wallace, L.; Rillema, D. P. Inorg. Chem. 1993, 32, 3836. (b) Worl, L. A.; Duesing, R.; Chen, P.; Delia Ciana, L.; Meyer, T. J. J. Chem. Soc., Dalton Trans. 1991, 843. Sacksteder, L.; Zipp, A. P.; Brown, E. A.; Streich, J.; Demas, J. N.; Degraff, B. A. Inorg. Chem. 1990, 29, 4335. Hino, J. K.; Della Ciana, L.; Dressick, W. J.; Sullivan, B. P. Inorg. Chem. 1992, 31, 1072. (e) Paulson, S.; Morris, K.; Sullivan, B. P. J. Chem. Soc., Chem. Commun. 1992, 1615. (f) Shaver, R. J.; Rillema, D. P. Inorg. Chem. 1992, 31, 4101. (g) Striplin, D. R.; Crosby, G. A. Chem. Phys. Lett. 1994, 227, 426.
12. Some leading references: (a) Wallace, L.; Rillema, D. P. Inorg. Chem. 1993, 32, 3836. (b) Worl, L. A.; Duesing, R.; Chen, P.; Delia Ciana, L.; Meyer, T. J. J. Chem. Soc., Dalton Trans. 1991, 843. Sacksteder, L.; Zipp, A. P.; Brown, E. A.; Streich, J.; Demas, J. N.; Degraff, B. A. Inorg. Chem. 1990, 29, 4335. Hino, J. K.; Della Ciana, L.; Dressick, W. J.; Sullivan, B. P. Inorg. Chem. 1992, 31, 1072. (e) Paulson, S.; Morris, K.; Sullivan, B. P. J. Chem. Soc., Chem. Commun. 1992, 1615. (f) Shaver, R. J.; Rillema, D. P. Inorg. Chem. 1992, 31, 4101. (g) Striplin, D. R.; Crosby, G. A. Chem. Phys. Lett. 1994, 227, 426.
13. Some leading references: (a) Wallace, L.; Rillema, D. P. Inorg. Chem. 1993, 32, 3836. (b) Worl, L. A.; Duesing, R.; Chen, P.; Delia Ciana, L.; Meyer, T. J. J. Chem. Soc., Dalton Trans. 1991, 843. Sacksteder, L.; Zipp, A. P.; Brown, E. A.; Streich, J.; Demas, J. N.; Degraff, B. A. Inorg. Chem. 1990, 29, 4335. Hino, J. K.; Della Ciana, L.; Dressick, W. J.; Sullivan, B. P. Inorg. Chem. 1992, 31, 1072. (e) Paulson, S.; Morris, K.; Sullivan, B. P. J. Chem. Soc., Chem. Commun. 1992, 1615. (f) Shaver, R. J.; Rillema, D. P. Inorg. Chem. 1992, 31, 4101. (g) Striplin, D. R.; Crosby, G. A. Chem. Phys. Lett. 1994, 227, 426.
14. Some leading references: (a) Wallace, L.; Rillema, D. P. Inorg. Chem. 1993, 32, 3836. (b) Worl, L. A.; Duesing, R.; Chen, P.; Delia Ciana, L.; Meyer, T. J. J. Chem. Soc., Dalton Trans. 1991, 843. Sacksteder, L.; Zipp, A. P.; Brown, E. A.; Streich, J.; Demas, J. N.; Degraff, B. A. Inorg. Chem. 1990, 29, 4335. Hino, J. K.; Della Ciana, L.; Dressick, W. J.; Sullivan, B. P. Inorg. Chem. 1992, 31, 1072. (e) Paulson, S.; Morris, K.; Sullivan, B. P. J. Chem. Soc., Chem. Commun. 1992, 1615. (f) Shaver, R. J.; Rillema, D. P. Inorg. Chem. 1992, 31, 4101. (g) Striplin, D. R.; Crosby, G. A. Chem. Phys. Lett. 1994, 227, 426.
15. Meyer, G. J., Ed. Molecular Level Artificial Photosynthetic Materials. Prog. Inorg. Chem. (Karlin, K. D., Ed.) 1996, 44.
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18. See, for example: (a) MacQueen, D. B.; Schanze, K. S. J. Am. Chem. Soc. 1991, 113, 6108-6110. (b) Shen, Y.; Sullivan, B. P. Inorg. Chem. 1995, 34, 6235. Shen, Y.; Sullivan, B. P. J. Chem. Educ. 1997, 74, 685.
19. See, for example: (a) MacQueen, D. B.; Schanze, K. S. J. Am. Chem. Soc. 1991, 113, 6108-6110. (b) Shen, Y.; Sullivan, B. P. Inorg. Chem. 1995, 34, 6235. Shen, Y.; Sullivan, B. P. J. Chem. Educ. 1997, 74, 685.
20. See, for example: (a) MacQueen, D. B.; Schanze, K. S. J. Am. Chem. Soc. 1991, 113, 6108-6110. (b) Shen, Y.; Sullivan, B. P. Inorg. Chem. 1995, 34, 6235. Shen, Y.; Sullivan, B. P. J. Chem. Educ. 1997, 74, 685.
21. See, for example: (a) Vining, W. J.; Caspar, J. V.; Meyer, T. J. J. Phys. Chem. 1985, 89, 1095. (b) Lang, J. M.; Dreger, Z. A.; Drickamer, H. G. Chem. Phys. Lett. 1992, 192, 299. Sullivan, B. P. J. Phys. Chem. 1989, 93, 24.
22. See, for example: (a) Vining, W. J.; Caspar, J. V.; Meyer, T. J. J. Phys. Chem. 1985, 89, 1095. (b) Lang, J. M.; Dreger, Z. A.; Drickamer, H. G. Chem. Phys. Lett. 1992, 192, 299. Sullivan, B. P. J. Phys. Chem. 1989, 93, 24.
23. See, for example: (a) Vining, W. J.; Caspar, J. V.; Meyer, T. J. J. Phys. Chem. 1985, 89, 1095. (b) Lang, J. M.; Dreger, Z. A.; Drickamer, H. G. Chem. Phys. Lett. 1992, 192, 299. Sullivan, B. P. J. Phys. Chem. 1989, 93, 24.
24. (a) Caspar, J. V. Ph.D. Dissertation. University of North Carolina, Chapel Hill, 1983. It was noted here that dicarbonyl Re(I) complexes had longer relative lifetimes than tricarbonyls.
25. (b) Caspar, J. V.; Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1984, 23, 2104.
26. (c) Luong, J. C. Ph.D. Dissertation, Massachsetts Institutue of Technology, 1981.
27. Caspar, J. V.; Meyer, T. J. J. Phys. Chem. 1983, 87, 952.
28. 2, and the filtrate was allowed to evaporate over a 48 h period. Ethyl ether was added to cause precipitation of the yellow product, which was subsequently filtered off and washed with 50 mL of ethyl ether. Anal. Calcd: C, 49.74; N, 2.90; H, 3.34. Found: C, 49.93; N, 2.83; H, 3.15.
29. 6. Anal. Calcd: C, 47.90; N, 3.02; H, 3.26 Found: C, 48.02; N, 3.09; H, 3.31,
30. 3(OTf) (155 mg, 0.27 mmol) and dppm (104 mg, 0.27 mmol) were placed in a 50 mL round bottom flask containing 10 mL of o-dichlorobenzene. The reaction mixture was purged with nitrogen for 30 min and refluxed for 5 h, after which time 40 mL of diethyl ether was added, following cooling. The yellow-orange solid which precipitated was collected and washed with ether, resulting in an orange oil. This oil was dissolved in dichloromethane and dropped into stirring ether, giving the yellow-orange product, which was collected, washed with ether, and air-dried (188 mg. 73% yield).
31. Woessner, S.; Sullivan, B. P. Work in progress.
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38. nr for both the tricabonyls and dicarbonyls must be done before any conclusion concerning the origin of the lifetime differences can be drawn.