메뉴 건너뛰기




Volumn 20, Issue 45, 1979, Pages 4343-4346

Stereo- and regioselective methods for the synthesis of three consecutive asymmetric units found in many natural products

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0001083151     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(01)86584-9     Document Type: Article
Times cited : (147)

References (20)
  • 9
    • 84918355732 scopus 로고    scopus 로고
    • See footnote 5 in the following paper.
  • 10
    • 84918355731 scopus 로고    scopus 로고
    • We consider this a case where it would be feasible to extend the chain of 1a–d from left to right but not from right to left; thus, 1b is not enantiomeric, but diastereomeric with 1c in this sense.
  • 11
    • 84918355730 scopus 로고    scopus 로고
    • Satisfactory spectroscopic data (ms, nmr, ir) were obtained for this substance.
  • 14
    • 0344361923 scopus 로고
    • Rules for ring closure
    • 2, that the steric hindrance mentioned plays a major role for observed regioselectivity, since the ring opening of ii under the same conditions yielded about a 1:1 mixture of two possible alcohols (C.-L. J. Wang and Y. Kishi, unpublished results).
    • (1976) Journal of the Chemical Society, Chemical Communications , pp. 734
    • Baldwin1
  • 15
    • 84918355729 scopus 로고    scopus 로고
    • The synthesis of cis, cis-3,5-dimethyl-4-hydroxycyclohexanone and its transformation to 7 and then to 11 were carried out by Dr. W. Rutsch in our laboratories.
  • 16
    • 84918355728 scopus 로고    scopus 로고
    • 6/RT gave a 1:1 ratio. Epoxidation of iii under both conditions also afforded a 3:2 isomer ratio.
  • 20
    • 84918355727 scopus 로고    scopus 로고
    • 2 in 12 and 13 with the hope that these polar groups might change the steric course of the reaction and give the products belonging to the type 1a or 1b. However, we found that the major product in all cases studied was the 1c or 1d type (C.-L. Wang and Y. Kishi, unpublished results).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.