Polyoxoanions derived from [γ-SiO4W10O 32]8- -Containing oxo-centered dinuclear chromium(III) carboxylato complexes: Synthesis and single-crystal structural determination of [γ-SiO4W10O32(OH)Cr2 (OOCCH3)2(OH2)2]5-

Inorganic Chemistry

Volumn 35, Issue 11, 1996, Pages 3273-3279

  Wassermann, Knut ^a,c   Lunk, Hans Joachim ^a,d   Palm, Rosemarie ^b   Fuchs, Joachim ^b   Steinfeldt, Norbert ^a   Stösser, Reinhard ^a   Pope, Michael T ^c  

^a HUMBOLDT UNIVERSITY   (Germany)

^b FREIE UNIVERSITÄT BERLIN   (Germany)

^c GEORGETOWN UNIVERSITY   (United States)

^d OSRAM SYLVANIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001081024     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9513954     Document Type: Article

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38. III complexes containing a carboxylato-bridged unit have been studied in recent years. (a) Tanase, T.; Lippard, S. T. Inorg. Chem. 1995, 34, 4682-4690. (b) Turowski, P. N.; Armstrong, W. H.; Liu, S., Brown, S. N.; Lippard, S. J. Inorg. Chem. 1994, 33, 636-645. (c) Kurtz, D. M., Jr. Chem. Rev. 1990, 90, 585-606 (d) Que, L., Jr.; True, A. E. Prog. Inorg. Chem. 1990, 38, 97-200. (e) Bossek, U.; Weyhermuller, T.; Wieghardt, K.; Bonvoisin, J.; Giererd, J. J. J. Chem. Soc., Chem. Commun. 1989, 633-636.
39. III complexes containing a carboxylato-bridged unit have been studied in recent years. (a) Tanase, T.; Lippard, S. T. Inorg. Chem. 1995, 34, 4682-4690. (b) Turowski, P. N.; Armstrong, W. H.; Liu, S., Brown, S. N.; Lippard, S. J. Inorg. Chem. 1994, 33, 636-645. (c) Kurtz, D. M., Jr. Chem. Rev. 1990, 90, 585-606 (d) Que, L., Jr.; True, A. E. Prog. Inorg. Chem. 1990, 38, 97-200. (e) Bossek, U.; Weyhermuller, T.; Wieghardt, K.; Bonvoisin, J.; Giererd, J. J. J. Chem. Soc., Chem. Commun. 1989, 633-636.
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49. III-substituted polyoxoanion.
50. 2v).
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56. + and corresponding intermediate states.
57. The structural analysis of carboxo acids gave the following bond distances and bond angles, respectively (data for formic acid): C=O, 1.20-1.28 Å (1.23 Å); C-OH, 1 25-1.31 Å (1.26 Å); O-C-OH, 122-126° (123.1°). Holtzberg, F.; Post, B.; Fankuchen, I. Acta Crystallogr. 1953, 6, 127-130.
58. + cation could not be refined.
59. We thank Prof. Charles O'Connor University of New Orleans for magnetic susceptibility measurements.