Spectra of the rare gas hydrides v: The np rydberg series of KrD

Molecular Physics

Volumn 81, Issue 2, 1994, Pages 291-326

  Dabrowski, I ^a   Sadovskii D A ^a,b  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

^b The College of William and Mary   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001075585     PISSN: 00268976     EISSN: 13623028     Source Type: Journal    
DOI: 10.1080/00268979400100201     Document Type: Article

References (40)

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9. 4 in [9] and [10]. In the case of ArD however, he was in favour of strong s∑-p∏ ‘Coriolis’ mixing rather than of a deformed p complex structure of type (2). In recent work [23], Watson has shown in detail that a large dipole moment of the core can indeed be the cause of s-p mixing. We discuss this subject in section 5.1.
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24. 2∏) complex. Our branch notation also makes use of the multiplicity indices, although N (or L) may often be used as an additional label.
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29. + have been measured most recently by LINNARTZ, H., HAVENITH, M., ZWART, E., LEO MEERTS, W., and TER MEULEN, J. J., 1992, J. molec. Spectrosc., 153, 710.
30. LAUGHLIN, K. B., BLAKE, G. A., COHEN, R. C., and SAYKALLY, R. J., 1989, J. chem. Phys., 90, 1358, respectively. Unfortunately there is no unique procedure to interpret the measurements, while vibrational corrections may run as high as 1 D, and experimental errors, ± 0·3-0·6 D. Thus, the resulting values lie in the range of µ = 2-3 D.
31. Ab initio calculations by ROSMUS, P., 1979, Theoret. chim. Acta, 51, 359.
32. +.
33. WATSON, J. K. G., 1994, Molec. Phys
34. Other Rydberg molecules with high polarized cores are alkaline earth halides such as CaF, BaF, CaCI, BaCI, … See for example, MURPHY, J. E., BERG, J. M., MERER, A. J., HARRIS, N. A., and FIELD, R. W., 1990, Phys. Rev. Lett., 65, 1861.
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38. VAN HEMERT, M. C., private communication.
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