Luminescence and resonance Raman study of molecular distortions caused by ligand-centered transitions in metal acetylacetonate complexes

Inorganic Chemistry

Volumn 35, Issue 13, 1996, Pages 4064-4066

  Wexler, David ^a   Zink, Jeffrey I ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001070647     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9501374     Document Type: Article

References (25)

1. Wexler, D.; Zink, J. I.; Tutt, L. W.; Lunt, S. R. J. Phys. Chem. 1993, 97, 13563.
2. Kodas, T. T. and Comita, P. B. Acc. Chem. Res. 1990, 23, 188.
3. Baum, T. H. and Larson, C. E. Chem. Mater. 1992, 4, 365.
4. Klassen, R. B.; Baum, T. H. Organomctallics 1989, 8, 2477.
5. Baum, T. H.; Jones, C. R. J. Vac. Sci. Technol. 1986, B4, 1187.
6. Wexler, D.; Zink. J. I. J. Phys. Chem. 1993, 97, 4903.
7. Halverson, F.; Bnnen, J. S.; Leto, J. R. J. Chem. Phys. 1964, 40, 2790.
8. Gafney, H. D.; Lintvedt, R. L.; Jaworiwsky, I. S. Inorg. Chem. 1970, 9, 1728.
9. Lintvedt, R. L. In Concepts and Models of Inorganic Photochemistry, Adamson, A. W., Fleischauer, P. D., Eds.; Wiley: New York, 1975; Chapter 7.
10. Heller, E. J. Acc. Chem. Res. 1981, 14, 368.
11. Heller, E. J. J. Chem. Phys. 1978, 68, 3891.
12. Heller, E. J. J. Chem Phys. 1978, 68, 2066.
13. Reber, C.; Zink, J. I. J. Chem. Phys 1992, 96, 2681.
14. Reber, C.; Zink. J. I. Comments Inorg. Chem. 1992, 13, 177.
15. Reber, C , Zink, J. I. Coord. Chem. Rev. 1991, 111, 1
16. Behnke. G. T.; Nakamoto, K. Inorg. Chem. 1967, 6, 433
17. Miles, M. G.; Glass, G. E ; Tobias, R. S. J. Am. Chem. Soc. 1966, 88, 5738.
18. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coor dination Compounds, 4th ed; Wiley and Sons: New York, 1986; p 260.
19. Nakamoto, K.; Morimoto, Y.; Martell, A. E. J. Phys. Chem. 1962, 66, 346.
20. Tang, J.; Albrecht, A. C. Raman Spectroscopy; Szynanski. H., Ed.; Plenum Press: New York, 1970; Vol. 2, p 33
21. Warshel, A ; Dauber, P. J Chem. Phys. 1977, 66, 5477.
22. Zink. J. I.; Kirn Shin, K.-S. Molecular Distortions in Excited Electronic States Determined from Electronic and Resonance Raman Spectroscopy. In Advances in Photochemistry; Volman, D. H.; Hamrnond, G S., Neckers, D. C., Eds., John Wiley & Sons: New York, 1991, Vol. 16 and reference therein.
23. 8Δ where M is the mass involved in the vibration in the units of gram atomic weight (e.g. C = 12 g), ω is the wavenumber of the vibrational mode in cm-1, ℏ = h/2π where h is Planck's constant in g cm2 s-1, c is the speed of light in cm s- l, δ the displacement in Å, and Δ is the dimensionless displacement. For example, the bond length change for the 1352 cm-1 mode is 0.01 Å when the reduced mass is approximated as 6 g.
24. Reber, C.; Zink, J. I. J. Chem. Phys. 1992, 96, 571.
25. Shin, K. S. K.; Zink, J. I. J. Am. Chem. Soc. 1990, 112, 7148.