Sterically Crowded Gallium Amidinate Complexes

Organometallics

Volumn 18, Issue 22, 1999, Pages 4619-4623

  Dagorne, Samuel ^a   Jordan, Richard F ^a,c   Young Jr , Victor G ^b  

^a E11 SSH   (United States)

^b University of Minnesota   (United States)

^c UNIVERSITY OF CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001039289     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990472q     Document Type: Article

References (25)

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3. (c) Ochi, A.; Bowen, H. K.; Rhine, W. E. Mater. Res. Soc. Symp. Proc. 1988, 121, 663.
4. (a) Coles, M. P.; Jordan, R. F. Organometallics 1997, 16, 5183.
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12. (i) Hausen, H. D.; Gerstner, F.; Schwarz, W. J. Organomet. Chem. 1978, 145, 277.
13. (a) Coles, M. P.; Jordan, R. F. J. Am. Chem. Soc. 1997, 34, 8125.
14. (b) Ihara, E.; Young, V. G., Jr.; Jordan, R. F. J. Am. Chem. Soc. 1998, 32, 8277.
15. (c) Radzewich, C. E.; Coles, M. P.; Jordan, R. F. J. Am. Chem. Soc. 1998, 120, 9384.
16. Dagorne, S.; Guzei, I.; Coles, M. P.; Jordan, R. F. Submitted for publication.
17. χGa = 1.8.
18. 6b are estimated to be 108° and 102°, respectively, on the basis of the crystallographic data for 2b,c and 3b and van der Waals radii taken from: Bondi, A. J. Phys. Chem. 1964, 68, 441. Therefore, the Cl-Ga-Cl angles in 2b,c would be predicted to be slightly larger than the C-Ga-C angle in 3b on the basis of steric effects.
19. (b) Tolman, C. A. Chem. Rev. 1977, 77, 313.
20. 3 cone angles given in ref 2a are θ/2 values.
21. (a) Bent, H. A. J. Chem. Educ. 1960, 37, 616.
22. (b) Bent, H. A. Chem. Rev. 1961, 61, 275.
23. Wallwork, S. C.; et al. J. Chem. Soc. 1965, 1816.
24. Beagley, B.; Schmidling, D. G.; Steer, I. A. J. Mol. Struct. 1974, 21, 437.
25. 2)-N single-bond distance (1.47 Å).