Existence of the Monomeric Cu(CN)32 Anion in the Solid State. Molecular Structure and Disorder of Sodium Tricyanocuprate(I) Trihydrate

Inorganic Chemistry

Volumn 17, Issue 7, 1978, Pages 1945-1949

  Kappenstein, Charles ^a   Hugel, René P ^a  

^a UNIVERSITÉ DE REIMS CHAMPAGNE ARDENNE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001037320     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic50185a050     Document Type: Article

References (18)

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2. C. Kappenstein, Thesis, Universite De Reims, 1977.
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4. W. P. Griffith in “Comprehensive Inorganic Chemistry”, Vol. 4, J. C. Bailar, Ed., Pergamon Press, Oxford, 1973.
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6. “International Tables for X-Ray Crystallography”, Vol. 3, Kynoch Press, Birmingham, England, 1962.
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8. The stereoview was computed on an IBM 1130 computer with a local program (C.K.) (after D. Y. Curtin, J. Chem. Educ., 50, 775 (1973)
9. These are the following phosphine and thiourea compounds: tris(trimethylphosphine sulfide)copper(I) perchlorate, Cu[SP(CH3)3]3C1O4, G. Eller and P. W. R. Corfield, Chem. Commun., 105 (1971)
10. (the chloride compound is dimeric); tris(ethylenethiourea)copper(I) sulfate, Cu[S-C3N2H6]3SO4 and tris(tetramethylthiourea)copper(I) tetrafluoroborate, Cu{SC[N(CH3)2]}3BF4, M. S. Weininger, G. W. Hunt and E. L. Amma, J. Chem. Soc., Chem. Commun., 1140 (1972).
11. Tris(2-picoline)copper(I) perchlorate, Cu(C6H7N)3C1O4: A. H. Lewin, R. J. Michl, P. Ganis and U. Lepore, J. Chem. Soc., Chem. Commun., 661 (1972).
12. Bromobis(triphenylphosphine)copper(I) hemibenzenate, [(C6H5)3P]2CuBr-1/2C6H6: P. H. Davis, R. L. Belford and I. C. Paul, Inorg. Chem., 12, 213 (1973).
13. Dichloro(acrylonitrile)dicopper(I), Cu2C12N≡CCH=CH2: M. Massaux, M. T. Le Bihan and R. Chevalier, Acta Crystallogr., Sect. B, 33, 2084 (1977).
14. G. Thiele, R. Bauer and D. Messer, Naturwissenschaften, 61, 215 (1974).
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